Dong Jie, Guo Hui, Hu Qiao-Sheng
Department of Chemistry, College of Staten Island of the City University of New York, Staten Island, New York 10314, United States.
Ph.D. Program in Chemistry, Graduate Center of the City University of New York, New York, New York 10016, United States.
ACS Macro Lett. 2017 Nov 21;6(11):1301-1304. doi: 10.1021/acsmacrolett.7b00759. Epub 2017 Nov 7.
Controlled Pd(0)-catalyzed Suzuki cross-coupling polymerizations of AB-type monomers with tris(1-adamantyl)phosphine (AdP) as the ligand was described. AdP-coordinated acetanilide-based palladacycle complex () was demonstrated to be an efficient initiator for controlled Suzuki cross-coupling polymerization, affording polymers with narrow s and well-controlled end groups. Our study provided an efficient ligand and an efficient initiator for controlled Suzuki cross-coupling polymerizations.
描述了以三（1-金刚烷基）膦（AdP）为配体的AB型单体的受控钯（0）催化铃木交叉偶联聚合反应。AdP配位的基于乙酰苯胺的钯环配合物（）被证明是用于受控铃木交叉偶联聚合反应的有效引发剂，可提供具有窄分子量分布和良好控制端基的聚合物。我们的研究为受控铃木交叉偶联聚合反应提供了一种有效的配体和一种有效的引发剂。
