通过三（螺硼酸酯）双碗状化合物的超分子链形成制备豆荚聚合物。
Preparation of Peapod Polymer via the Supramolecular Chain Formation by Tris(spiroborate) Twin Bowl.
作者信息
Danjo Hiroshi, Nakagawa Toshi, Morii Akio, Muraki Yusuke, Sudoh Koichi
机构信息
The Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan.
出版信息
ACS Macro Lett. 2017 Jan 17;6(1):62-65. doi: 10.1021/acsmacrolett.6b00972. Epub 2017 Jan 6.
Successive guest-containing tubular polymer was prepared by the olefin metathesis polymerization of tris(spiroborate) twin bowl after the formation of supramolecular polymer. The cationic iridium(III) complexes were topologically fixed inside the polymer to form a peapod-like structure. The polymer was evaluated by SEC, ICP-AES, and DLS analyses, and string-like structures were found in the AFM observation of the peapod polymer.
在超分子聚合物形成后，通过三（螺硼酸酯）双碗状化合物的烯烃复分解聚合制备了连续的含客体管状聚合物。阳离子铱（III）配合物在拓扑学上固定在聚合物内部，形成一种豆荚状结构。通过尺寸排阻色谱（SEC）、电感耦合等离子体原子发射光谱（ICP - AES）和动态光散射（DLS）分析对该聚合物进行了评估，并且在豆荚状聚合物的原子力显微镜（AFM）观察中发现了线状结构。
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