The Mechanism of Cu Sorption by Rice Straw Biochar and Its Sorption-Desorption Capacity to Cu in Soil.

Copper (Cu) pollution in soils has received considerable research attention globally, and biochar has been widely used as an adsorbent for soil pollution of Cu. However, most of the studies focused on the adsorption capacity of biochar, the bioavailability of Cu absorbed by biochar remains unclear. In this work, rice straw biomass was pyrolyzed under oxygen-limited conditions at 400°C (BC400) and 600°C (BC600), their apparent structure, group characteristics, and basic physical and chemical properties were determined. The isothermal and kinetics adsorption of Cu by BC400 and BC600 were analyzed. A pot experiment was used to evaluate the passivation of Cu in the soil by biochar and the bioavailability of Cu adsorbed by biochar in the soil. The smooth surfaces of BC400 evolved into more rough surfaces for BC600, and both types of surfaces may give active sorption sites for Cu, according to SEM pictures. FTIR analysis suggested that BC600 is endowed with more condensed aromatic carbon structures and more available polar functional groups. The adsorption processes of Cu by biochar were better fitted Langmuir equation and pseudo-second-order kinetic model. The adsorption isotherms showed monolayer adsorption of Cu on biochar. The maximum adsorption capacities of BC600 and BC400 on Cu were 43.75 and 30.70 mg g, respectively. Moreover, the pot experiment showed that BC400 and BC600 not only have a strong "passivation" effect on Cu in soil but also prevent the release of adsorbed Cu. Overall, more aromatic carbon structure, more polar functional groups, and higher pH are associated with BC600's increased Cu immobilization ability in soil.