Moldenhauer Fenja, Kakuchi Ryohei, Theato Patrick
Institute for Technical and Macromolecular Chemistry, University of Hamburg, D-20146 Hamburg, Germany.
Faculty of Natural System, Institute of Science and Engineering, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
ACS Macro Lett. 2016 Jan 19;5(1):10-13. doi: 10.1021/acsmacrolett.5b00720. Epub 2015 Dec 8.
Kabachnik-Fields reaction was employed as a new method for polycondensation. For this purpose, polymers were prepared from a mixture of dialdehydes, diamines, and phosphites. Variation of different starting monomers allowed the synthesis of polymers with tunable properties. It not only allowed the variation of glass transition temperatures but also enabled the synthesis of highly functional polymers including zwitterionic polymers. Further, photodegradable polymers have been realized by utilizing a photolabile dialdehyde monomer, which renders the obtained polymers highly interesting for numerous applications.
卡巴奇尼克-菲尔德斯反应被用作一种新的缩聚方法。为此，由二醛、二胺和亚磷酸酯的混合物制备聚合物。不同起始单体的变化使得能够合成具有可调性能的聚合物。它不仅允许玻璃化转变温度的变化，还能够合成包括两性离子聚合物在内的高功能聚合物。此外，通过使用光不稳定的二醛单体实现了光降解聚合物，这使得所得聚合物在众多应用中极具吸引力。
