分子内氢键活化：催化中的策略、优势及影响
Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis.
作者信息
Guerrero-Corella Andrea, Fraile Alberto, Alemán José
机构信息
Organic Chemistry Department, Módulo 1, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, 28049 Madrid, Spain.
出版信息
ACS Org Inorg Au. 2022 Jun 1;2(3):197-204. doi: 10.1021/acsorginorgau.1c00053. Epub 2022 Feb 3.
The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction has enabled reactivity enhancement of reagents, as well as stabilization of the chemical species and enantiocontrol of the processes.
通过分子内氢键形成来活化分子以促进化学反应，这在有机合成中似乎是一种合适的策略，特别是在金属和有机催化条件下制备手性化合物时。这种相互作用的应用能够提高试剂的反应活性，以及稳定化学物种并实现过程的对映体控制。
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