Dal Poggetto Giovanni, D'Angelo Antonio, Catauro Michelina, Barbieri Luisa, Leonelli Cristina
Department of Engineering "Enzo Ferrari", University of Modena and Reggio Emilia, 41125 Modena, Italy.
Department of Engineering, University of Campania "Luigi Vanvitelli", 81031 Aversa, Italy.
Polymers (Basel). 2022 May 27;14(11):2173. doi: 10.3390/polym14112173.
Recycling corundum abrasive powder in metakaolin-based geopolymer formulations is proposed to reduce the amount of waste to be treated or disposed of in landfills, allowing to decrease ecological damage as well as to reduce transport costs for removal. The addition of waste corundum, as an important source of AlO, has proved to increase the slight ionic conductivity of the leachate solution obtained after immersion in water of samples at 28 d of curing at room temperature. With the same curing conditions, the geopolymerization process has not been disturbed as evidenced by the FT-IR peak shift and XRD patterns. It was recorded a decrease in resistance to compression of the consolidated geopolymers of about 5% with 10 wt% addition and of about 77% with the addition of 20 wt% of waste corundum. In any case, the waste abrasive powder does not release heavy metals when added to a geopolymeric formulation based on MK, NaOH, and Na-silicate, and does not show relevant antibacterial properties, indicating the formation of a stable and safe final product with a ceramic-like appearance.
有人提出在偏高岭土基地质聚合物配方中回收刚玉磨料粉,以减少需在垃圾填埋场处理或处置的废物量,从而减少生态破坏并降低清除的运输成本。作为氧化铝的重要来源,添加废刚玉已证明可提高在室温下养护28天后将样品浸入水中所获得的浸出液的轻微离子电导率。在相同的养护条件下,傅里叶变换红外光谱(FT-IR)峰位移动和X射线衍射(XRD)图谱表明地聚合过程未受干扰。记录显示,添加10 wt%废刚玉时,固结地质聚合物的抗压强度降低约5%,添加20 wt%废刚玉时降低约77%。无论如何,当将废磨料粉添加到基于偏高岭土、氢氧化钠和硅酸钠的地质聚合物配方中时,它不会释放重金属,也不显示相关的抗菌性能,表明形成了具有陶瓷外观的稳定且安全的最终产品。