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钐、铕掺杂的钇锆石基质的发光研究:黄绿色至红色可调谐焦绿石磷光体的光学研究

Luminescence study of Sm ,Eu -doped Y Zr O host: optical investigation of greenish yellow to red colour tunable pyrochlore phosphor.

作者信息

Bansod Amit R, Kadam Abhijeet R, Bokare Prashant S, Dhoble Sanjay J

机构信息

Department of Physics, Dr. Ambedkar College, Deekshabhoomi, Nagpur, India.

Department of Physics, R.T.M. Nagpur University, Nagpur, India.

出版信息

Luminescence. 2022 Aug;37(8):1352-1360. doi: 10.1002/bio.4305. Epub 2022 Jun 24.

Abstract

Pyrochlore phosphors have shown their worth in modern day lighting in the last few years. Colour tunability of the phosphor is one of the modern techniques used to obtain white light-emitting diodes (WLEDs). In the proposed work, Y Zr O :Sm ,Eu phosphors were investigated for WLED applications as well as display devices. A convectional solid-state diffusion method was used to synthesize the proposed phosphors. X-ray diffraction of the proposed phosphors was performed and compared with the standard Inorganic Crystal Structure Database. The crystal structure of the sample was cubic in nature, obtained from Rietveld refinement. Vibrational and morphological studies on the samples were carried out using Fourier transform infrared spectroscopy and scanning electron microscopy analysis. The photoluminescence study of the colour tunable phosphor showed the characteristic peak of Sm together with the two sharp peaks of Eu ions. Greenish yellow to red colour tunability was observed in the proposed phosphor with enhancement of Eu ions. All these results showed the worth of this sample for WLEDs applications as well as in display devices.

摘要

在过去几年中,烧绿石荧光粉已在现代照明领域展现出其价值。荧光粉的颜色可调性是用于获得白光发光二极管(WLED)的现代技术之一。在本研究中,对 Y Zr O :Sm ,Eu 荧光粉进行了 WLED 应用以及显示设备方面的研究。采用传统的固态扩散法合成了所提出的荧光粉。对所制备的荧光粉进行了 X 射线衍射分析,并与标准无机晶体结构数据库进行了比较。通过 Rietveld 精修获得的样品晶体结构为立方晶系。使用傅里叶变换红外光谱和扫描电子显微镜分析对样品进行了振动和形态学研究。对颜色可调荧光粉的光致发光研究显示了 Sm 的特征峰以及 Eu 离子的两个尖锐峰。在所提出的荧光粉中,随着 Eu 离子的增加,观察到了从黄绿色到红色的颜色可调性。所有这些结果表明该样品在 WLED 应用以及显示设备方面具有价值。

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