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Sm、Eu 激活/共激活的 BaAlBOCl 荧光粉的发光研究:氯硼酸盐中新型的从红色到蓝色的颜色调谐

Luminescence investigation of Sm ,Eu -activated/co-activated Ba AlB O Cl phosphors: novel red to blue colour tuning in chloroborates.

作者信息

Bansod Amit R, Kadam Abhijeet R, Bokare Prashant S, Dhoble Sanjay J

机构信息

Department of Physics, Dr. Ambedkar College, Deekshabhoomi, Nagpur, India.

Department of Physics, R.T.M. Nagpur University, Nagpur, India.

出版信息

Luminescence. 2022 Dec;37(12):2090-2097. doi: 10.1002/bio.4397. Epub 2022 Nov 7.

Abstract

Borochlorate phosphors have shown their worth in modern day lighting over the last few years. Colour tunability of the phosphor is a modern techniques used to obtain white-light-emitting diodes (WLEDs). In the proposed work, Sm ,Eu -activated/co-activated Ba AlB O Cl phosphors were investigated for WLED applications as well as display devices. A convectional solid-state diffusion method was used to synthesize the proposed phosphors. X-ray diffraction (XRD) of the proposed phosphors confirmed the crystalline nature of the sample. Morphological studies on the samples were carried out using scanning electron microscopy analysis. A photoluminescence study of the colour tunable phosphor showed the characteristic peak of Sm together with one broad peak for Eu ions. Red to blue colour tunability was observed in the proposed phosphor with enhancement of Eu ions. All these results showed the worth of this sample in WLED applications as well as in display devices.

摘要

在过去几年中,硼氯酸盐荧光粉已在现代照明领域展现出其价值。荧光粉的颜色可调性是用于获得白光发光二极管(WLED)的一项现代技术。在本研究中,对Sm、Eu激活/共激活的BaAlBOCl荧光粉进行了研究,用于WLED应用以及显示设备。采用传统的固态扩散法合成了所提出的荧光粉。所制备荧光粉的X射线衍射(XRD)证实了样品的晶体性质。使用扫描电子显微镜分析对样品进行了形态学研究。对颜色可调荧光粉的光致发光研究显示了Sm的特征峰以及Eu离子的一个宽峰。在所提出的荧光粉中,随着Eu离子含量的增加,观察到了从红色到蓝色的颜色可调性。所有这些结果表明该样品在WLED应用以及显示设备中具有价值。

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