Li Jia, Chen Yang, He Quanfeng, Xu Xiandong, Wang Hang, Jiang Chao, Liu Bin, Fang Qihong, Liu Yong, Yang Yong, Liaw Peter K, Liu Chain T
State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, College of Mechanical and Vehicle Engineering, Hunan University, Changsha 410082, China.
Department of Mechanical Engineering, College of Engineering, City University of Hong Kong, Kowloon Tong, Kowloon, Hong Kong SAR 999077, China.
Proc Natl Acad Sci U S A. 2022 Jun 21;119(25):e2200607119. doi: 10.1073/pnas.2200607119. Epub 2022 Jun 13.
Multi-principal element alloys (MPEAs) exhibit outstanding mechanical properties because the core effect of severe atomic lattice distortion is distinctly different from that of traditional alloys. However, at the mesoscopic scale the underlying physics for the abundant dislocation activities responsible for strength-ductility synergy has not been uncovered. While the Eshelby mean-field approaches become insufficient to tackle yielding and plasticity in severely distorted crystalline solids, here we develop a three-dimensional discrete dislocation dynamics simulation approach by taking into account the experimentally measured lattice strain field from a model FeCoCrNiMn MPEA to explore the heterogeneous strain-induced strengthening mechanisms. Our results reveal that the heterogeneous lattice strain causes unusual dislocation behaviors (i.e., multiple kinks/jogs and bidirectional cross slips), resulting in the strengthening mechanisms that underpin the strength-ductility synergy. The outcome of our research sheds important insights into the design of strong yet ductile distorted crystalline solids, such as high-entropy alloys and high-entropy ceramics.
多主元合金(MPEAs)表现出优异的力学性能,因为严重原子晶格畸变的核心效应与传统合金明显不同。然而,在介观尺度上,导致强度-延展性协同效应的丰富位错活动的潜在物理机制尚未被揭示。虽然埃舍尔比平均场方法不足以解决严重畸变晶体固体中的屈服和塑性问题,但在此我们通过考虑从模型FeCoCrNiMn多主元合金实验测量得到的晶格应变场,开发了一种三维离散位错动力学模拟方法,以探索非均匀应变诱导的强化机制。我们的结果表明,非均匀晶格应变会导致异常的位错行为(即多重扭折/割阶和双向交滑移),从而产生支撑强度-延展性协同效应的强化机制。我们的研究结果为设计强韧的畸变晶体固体(如高熵合金和高熵陶瓷)提供了重要见解。