Yao Xiaohui, Chen Shaozhan, Zhang Yong, Gao Wenrui, Zhou Tianhui, Liu Yang, Liu Liping
Beijing Center for Disease Prevention and Control, Beijing 100013, China.
Ankang Center for Disease Prevention and Control, Ankang 725003, China.
Wei Sheng Yan Jiu. 2022 May;51(3):437-462. doi: 10.19813/j.cnki.weishengyanjiu.2022.03.016.
To understand the distribution characteristics of 46 elements in drinking water in Ankang area of Shanxi Province.
A total of 46 elements in drinking water samples collected in Ankang area during dry and wet seasons in 2020 were determined by inductively coupled plasma mass spectrometry(ICP-MS). According to the "drinking water hygiene standards"(GB 5749-2022) and "food safety national standards". the 46 elements were classified As general chemical indexes(Al, Mn, Fe, Cu, Zn), toxicological indexes(Cr, As, Cd, Hg, Pb, Ba, B, Mo, Ni, Sb, Be, Ag, Tl), new reference indexes(U, V), and major elements(K, Ca, N) A, Mg), trace elements(Li, Co, Se, Sr, Sn) and rare earth elements(Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th) were analyzed and described.
The maximum values of Al and Fe in drinking water in Ankang area were 1.21 and 0.98 mg/L, exceeding the limits of 0.2 and 0.3 mg/L. In dry season, the median content of Fe in drinking water of different water sources was higher in groundwater than in surface water. The Al and Fe of surface water were higher than that of groundwater in wet season. The toxicological indexes all met the standard requirements, and there was no significant difference among districts and counties. The median content of Na in drinking water of different water sources was higher in groundwater than in surface water, while Mg, K and Ca were higher in surface water than in groundwater. The maximum value of the newly added reference index U was 0.015 mg/L lower than the limit standard 0.03 mg/L, and the maximum value of V was 0.019 mg/L higher than the limit standard 0.01 mg/L, but the median of both indexes were low. The median content of Li in drinking water of different water sources was that surface water was higher than groundwater, while Se and Sr were higher in groundwater than surface water. The maximum content of Se was 0.016 mg/L in Ziyang County, and Sr content was generally higher. The content of rare earth elements was low, mostly below the detection.
The drinking water quality in Ankang area is excellent and rich in strontium. However, the general chemical indexes Al, Fe and the newly added appendix index V in some sampling points exceed the limit standard, so supervision and monitoring should be strengthened.
了解陕西省安康地区饮用水中46种元素的分布特征。
采用电感耦合等离子体质谱法(ICP-MS)测定2020年安康地区枯水期和丰水期采集的饮用水样品中的46种元素。依据《生活饮用水卫生标准》(GB 5749-2022)和《食品安全国家标准》,将这46种元素分为一般化学指标(铝、锰、铁、铜、锌)、毒理学指标(铬、砷、镉、汞、铅、钡、硼、钼、镍、锑、铍、银、铊)、新增参考指标(铀、钒)、常量元素(钾、钙、钠、镁)、微量元素(锂、钴、硒、锶、锡)以及稀土元素(钪、钇、镧、铈、镨、钕、钐、铕、钆、铽、镝、钬、铒、铥、镱、镥、钍)进行分析描述。
安康地区饮用水中铝和铁的最大值分别为1.21和0.98mg/L,超过了0.2和0.3mg/L的限值。枯水期不同水源饮用水中铁的中位数含量在地下水中高于地表水。丰水期地表水的铝和铁含量高于地下水。毒理学指标均符合标准要求,各区县之间无显著差异。不同水源饮用水中钠的中位数含量在地下水中高于地表水,而镁、钾和钙在地表水中高于地下水。新增参考指标铀的最大值比限值标准0.03mg/L低0.015mg/L,钒的最大值比限值标准0.01mg/L高0.019mg/L,但两者的中位数均较低。不同水源饮用水中锂的中位数含量是地表水高于地下水,而硒和锶在地下水中高于地表水。紫阳县硒的最大含量为0.016mg/L,锶含量普遍较高。稀土元素含量较低,大多低于检测限。
安康地区饮用水水质优良,富含锶。然而,部分采样点的一般化学指标铝、铁以及新增附录指标钒超过限值标准,应加强监督监测。