Institute of Agrochemistry and Food Technology (IATA-CSIC), C/Agustin Escardino, 7, 46980 Paterna, Valencia, Spain.
Department of Chemical Engineering, Universidade de Santiago de Compostela, rúa Lope Gómez de Marzoa, Santiago de Compostela, E-15782, Spain.
Food Funct. 2022 Jul 18;13(14):7582-7590. doi: 10.1039/d2fo00697a.
Starch is one of the most important carbohydrates that is present in many foods. Gelatinization is an important property of starch, associated with physical changes that promote an increase in viscosity. The objective of this research was to understand how the viscosity of starch gels affects their hydrolysis and whether that effect was dependent on the type of starch. Different gels (corn, wheat, and rice) with variable or constant viscosity were analyzed using diverse methodologies to determine the changes in the pasting behavior. A rapid force analyzer, a vibration viscometer and a rheometer were used to differentiate the gels based on the starch source and concentration. At a fixed starch concentration, corn gel displayed the highest viscosity, slowing the enzymatic starch hydrolysis. The higher viscosity of those gels prepared with a fixed starch concentration significantly enhanced the slowly digestible starch (SDS) and reduced the kinetic constant (). Nevertheless, gels with constant viscosity (550 mPa s) showed comparable hydrolysis kinetics, obtaining similar SDS, total hydrolyzed starch and . The correlation matrix confirmed the relationship between and gel viscosity ( = -0.82), gelatinization rate (-slope) ( = -0.87), breakdown ( = -0.84) and elastic modulus (' 37 °C) ( = -0.73). Therefore, these parameters could be used as predictors of the hydrolysis performance of starch gels as well as in reverse engineering for the design of healthy foods.
淀粉是存在于许多食物中的最重要的碳水化合物之一。糊化是淀粉的一个重要性质,与促进粘度增加的物理变化有关。本研究的目的是了解淀粉凝胶的粘度如何影响其水解,以及这种影响是否取决于淀粉的类型。使用不同的方法学分析了具有不同粘度的不同凝胶(玉米、小麦和大米),以确定糊化行为的变化。使用快速力分析仪、振动粘度计和流变仪根据淀粉来源和浓度对凝胶进行区分。在固定淀粉浓度下,玉米凝胶表现出最高的粘度,减缓了酶促淀粉水解。那些用固定淀粉浓度制备的凝胶的较高粘度显著增加了缓慢消化淀粉(SDS)并降低了动力学常数()。然而,具有恒定粘度(550 mPa s)的凝胶显示出可比的水解动力学,获得相似的 SDS、总水解淀粉和。相关矩阵证实了和凝胶粘度(= -0.82)、糊化速率(-斜率)(= -0.87)、崩解(= -0.84)和弹性模量('37 °C)(= -0.73)之间的关系。因此,这些参数可用于预测淀粉凝胶水解性能,以及作为设计健康食品的反向工程的指标。