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用于室温电子气体传感器的有机/无机基柔性膜

Organic/Inorganic-Based Flexible Membrane for a Room-Temperature Electronic Gas Sensor.

作者信息

AlTakroori Husam H D, Ali Ashraf, Greish Yaser E, Qamhieh Naser, Mahmoud Saleh T

机构信息

Department of Physics, United Arab Emirates University, Al-Ain 15551, United Arab Emirates.

Department of Chemistry, United Arab Emirates University, Al-Ain 15551, United Arab Emirates.

出版信息

Nanomaterials (Basel). 2022 Jun 14;12(12):2037. doi: 10.3390/nano12122037.

DOI:10.3390/nano12122037
PMID:35745376
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9227867/
Abstract

A room temperature (RT) HS gas sensor based on organic-inorganic nanocomposites has been developed by incorporating zinc oxide (ZnO) nanoparticles (NPs) into a conductivity-controlled organic polymer matrix. A homogeneous solution containing poly (vinyl alcohol) (PVA) and ionic liquid (IL) and further doped with ZnO NPs was used for the fabrication of a flexible membrane (approx. 200 μm in thickness). The sensor was assessed for its performance against hazardous gases at RT (23 °C). The obtained sensor exhibited good sensitivity, with a detection limit of 15 ppm, and a fast time response (24 ± 3 s) toward HS gas. The sensor also showed excellent repeatability, long-term stability and selectivity toward HS gas among other test gases. Furthermore, the sensor depicted a high flexibility, low cost, easy fabrication and low power consumption, thus holding great promise for flexible electronic gas sensors.

摘要

通过将氧化锌(ZnO)纳米颗粒(NPs)掺入到电导率可控的有机聚合物基质中,开发出了一种基于有机-无机纳米复合材料的室温(RT)硫化氢气体传感器。一种含有聚乙烯醇(PVA)和离子液体(IL)并进一步掺杂ZnO NPs的均匀溶液被用于制备柔性膜(厚度约为200μm)。在室温(23°C)下评估了该传感器对有害气体的性能。所获得的传感器表现出良好的灵敏度,检测限为15 ppm,对硫化氢气体的响应时间快(24±3 s)。该传感器对硫化氢气体在其他测试气体中还表现出优异的重复性、长期稳定性和选择性。此外,该传感器具有高柔韧性、低成本、易于制造和低功耗等特点,因此在柔性电子气体传感器方面具有很大的前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/875335662ba2/nanomaterials-12-02037-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/dba04428adea/nanomaterials-12-02037-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/11aa4a369326/nanomaterials-12-02037-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/4df7ed7aae29/nanomaterials-12-02037-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/a0dcd33b7763/nanomaterials-12-02037-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/a5b32276be1d/nanomaterials-12-02037-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/020bf8577323/nanomaterials-12-02037-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/56b8308bab9f/nanomaterials-12-02037-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/875335662ba2/nanomaterials-12-02037-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/dba04428adea/nanomaterials-12-02037-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/11aa4a369326/nanomaterials-12-02037-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/4df7ed7aae29/nanomaterials-12-02037-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/a0dcd33b7763/nanomaterials-12-02037-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/a5b32276be1d/nanomaterials-12-02037-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/020bf8577323/nanomaterials-12-02037-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/56b8308bab9f/nanomaterials-12-02037-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fae/9227867/875335662ba2/nanomaterials-12-02037-g008.jpg

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A Highly Sensitive and Flexible Metal-Organic Framework Polymer-Based HS Gas Sensor.
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ACS Omega. 2021 Jun 30;6(27):17690-17697. doi: 10.1021/acsomega.1c02295. eCollection 2021 Jul 13.
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ZnO Nanosheets Abundant in Oxygen Vacancies Derived from Metal-Organic Frameworks for ppb-Level Gas Sensing.基于金属有机框架衍生的富含氧空位的氧化锌纳米片用于 ppb 级别的气体传感。
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