Fang Youting, Liu Ting, Chen Longxin, Chao Duobin
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 315211, Zhejiang, China.
Chem Commun (Camb). 2022 Jul 14;58(57):7972-7975. doi: 10.1039/d2cc02356c.
The consecutive photoinduced electron transfer (ConPET) process of 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in CO photoreduction to achieve powerful reducing species has been disclosed by activating a bis(terpyridine)ruthenium(II) complex bearing a high overpotential for selective light-driven reduction of CO to CO in homogeneous solution.
通过活化一种在均相溶液中对将CO选择性光驱动还原为CO具有高过电位的双（三联吡啶）钌（II）配合物，揭示了1,2,3,5-四（咔唑-9-基）-4,6-二氰基苯（4CzIPN）在CO光还原中实现强还原物种的连续光诱导电子转移（ConPET）过程。
