利用一氧化碳光还原中的连续光诱导电子转移（ConPET）。
Exploiting consecutive photoinduced electron transfer (ConPET) in CO photoreduction.
作者信息
Fang Youting, Liu Ting, Chen Longxin, Chao Duobin
机构信息
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 315211, Zhejiang, China.
出版信息
Chem Commun (Camb). 2022 Jul 14;58(57):7972-7975. doi: 10.1039/d2cc02356c.
PMID:35758170
Abstract
The consecutive photoinduced electron transfer (ConPET) process of 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in CO photoreduction to achieve powerful reducing species has been disclosed by activating a bis(terpyridine)ruthenium(II) complex bearing a high overpotential for selective light-driven reduction of CO to CO in homogeneous solution.
摘要
通过活化一种在均相溶液中对将CO选择性光驱动还原为CO具有高过电位的双（三联吡啶）钌（II）配合物，揭示了1,2,3,5-四（咔唑-9-基）-4,6-二氰基苯（4CzIPN）在CO光还原中实现强还原物种的连续光诱导电子转移（ConPET）过程。
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