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用于检测铬离子的有机荧光和比色化学传感器的最新进展综述

A Review on Recent Progress in Organic Fluorimetric and Colorimetric Chemosensors for the Detection of CrIons.

作者信息

Algethami Jari S

机构信息

Department of Chemistry, College of Science and Arts, Najran University, Najran, Saudi Arabia.

出版信息

Crit Rev Anal Chem. 2024;54(3):487-507. doi: 10.1080/10408347.2022.2082242. Epub 2022 Jun 26.

Abstract

Chromium occurs in the environment primarily in two valence states, trivalent Cr and hexavalent Cr, which have different physicochemical and biochemical properties. However, the higher concentration of Cr can cause various adverse effects on human health. Therefore, detecting Cr ions is important in various samples. Colorimetric and fluorescent chemosensors are the most powerful tools for the detection of Cr ions. These chemosensors have excellent bioimaging capability and significant sensitivity and selectivity. In this article, different colorimetric and fluorescent chemosensors based on organic compounds, including Schiff base, antipyrine, diarylethene, pyrene, crown ether, dansyl, pyridine, thiazole, coumarin, boradiazaindacene, rhodamine, imidazole, hydrazone, and other functional groups for detection of Cr ions have been reviewed, classified them according to different fluorophore and recognition mode. I hope this article will help the readers for the future design of highly effective, sensitive, and selective chemosensors for the detection and determination of Cr ions.

摘要

铬在环境中主要以两种价态存在,即三价铬和六价铬,它们具有不同的物理化学和生化性质。然而,较高浓度的铬会对人体健康造成各种不利影响。因此,检测各种样品中的铬离子很重要。比色和荧光化学传感器是检测铬离子最强大的工具。这些化学传感器具有出色的生物成像能力以及显著的灵敏度和选择性。本文综述了基于有机化合物的不同比色和荧光化学传感器,包括用于检测铬离子的席夫碱、安替比林、二芳基乙烯、芘、冠醚、丹磺酰基、吡啶、噻唑、香豆素、硼二氮杂茚、罗丹明、咪唑、腙及其他官能团,并根据不同的荧光团和识别模式对它们进行了分类。希望本文能帮助读者未来设计出用于检测和测定铬离子的高效、灵敏和选择性的化学传感器。

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