Designing Photothermal Superhydrophobic PET Fabrics via In Situ Polymerization and 1,4-Conjugation Addition Reaction.

This study demonstrates a simple and fast method to integrate superhydrophobicity, UV protection, and photothermal effect onto PET fabrics. The surface of PET fabric forms a hierarchical rough structure through in situ oxidative polymerization of the pyrrole (Py). The 1,4-conjugate addition reaction between pentaerythritol tetraacrylate, 3-aminopropyltriethoxysilane, and octadecyl acrylate not only endows the PET fabric with superhydrophobicity but also forms a cross-linked network structure which improves the stability of multifunctional coatings on the surface of the PET fabric. In addition, the wettability of the prepared PET fabric is investigated by adjusting the Py monomer and octadecyl acrylate concentration. The results reveal that the prepared PET fabrics exhibit obviously superhydrophobic behavior with a contact angle of 155.8°. The surface temperature of the superhydrophobic PPy/PET fabric can rise to 91 °C under a simulated sunlight which is much higher than the pristine PET fabric, while reaching basically the same steady-state in five heating/cooling cycles. The prepared PET fabric also possesses excellent self-cleaning, UV shielding, and solar light absorption performances. Furthermore, the superhydrophobic PET fabric exhibited excellent stability against 180 °C high temperature, strong UV radiation, different pH solutions and organic solvent erosion, 8 h washing tests, and 25 sandpaper abrasion cycles. These findings provide a path for the future development of multifunctional fabrics using fluorine-free environmentally friendly materials.