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低温条件下带有纳米线的聚丙烯及聚丙烯/聚(乙烯-辛烯)复制品表面的水冲击动力学及机理分析

Water Impact Dynamics and Mechanism Analysis of Polypropylene and Polypropylene/poly(ethylene--octene) Replica Surfaces with Nanowires under Low Temperature Conditions.

作者信息

Wang Xing-Yu, Huang Han-Xiong

机构信息

Lab for Micro Molding and Polymer Rheology, Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing, South China University of Technology, Guangzhou 510640, P. R. China.

出版信息

ACS Omega. 2024 Jul 22;9(30):33064-33071. doi: 10.1021/acsomega.4c04128. eCollection 2024 Jul 30.

Abstract

In this work, polypropylene (PP) and PP/poly(ethylene--octene) (PP/POE) blend replica surfaces with densely arranged nanowires are fabricated using a molding process. Morphology analysis shows that the nanowires on these replica surfaces have sharp tips and high aspect ratios. The droplet impact behaviors on the surfaces of the PP/POE blend replicas and PP replicas are investigated before and after freezing at -20 °C for 4 h. The height of the nanowires on the PP/POE blend replica surfaces is higher than that on the PP surface before and after freezing. The static wettability and droplet impact tests on the surfaces of PP/POE blend replicas and PP replica show that adding POE into the PP matrix can significantly increase the toughness of the nanowires on the PP/POE blend replica surfaces during the droplet impact at low temperatures. These investigations are favorable to broaden the practical applications of superhydrophobic surfaces in some severe environments.

摘要

在这项工作中,采用模塑工艺制备了具有密集排列纳米线的聚丙烯(PP)和PP/聚(乙烯-辛烯)(PP/POE)共混物复制表面。形态分析表明,这些复制表面上的纳米线具有尖锐的尖端和高纵横比。研究了PP/POE共混物复制体和PP复制体表面在-20°C下冷冻4小时前后的液滴冲击行为。冷冻前后,PP/POE共混物复制体表面纳米线的高度均高于PP表面。对PP/POE共混物复制体和PP复制体表面的静态润湿性和液滴冲击测试表明,在PP基体中添加POE可以显著提高低温下液滴冲击时PP/POE共混物复制体表面纳米线的韧性。这些研究有利于拓宽超疏水表面在一些恶劣环境中的实际应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a4d/11292825/2005b3d3a5d1/ao4c04128_0001.jpg

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