Selective capture of ammonium ions from municipal wastewater treatment plant effluent with a nickel hexacyanoferrate electrode.

Currently, intercalation materials such as Prussian blue analogs have attracted considerable attention in water treatment applications due to their excellent size-based selectivity toward cations. This study aimed to explore the feasibility of using a nickel hexacyanoferrate (NiHCF) electrode for selective NH capture from effluent from a municipal wastewater treatment plant. To assess the competitive intercalation between NH and other common cations (Na, Ca), a NiHCF//activated carbon (AC) hybrid capacitive deionization (CDI) cell was established to treat mixed-salt solutions. The results of cyclic voltammetry (CV) analysis showed a higher current response of the NiHCF electrode toward NH ions than toward Na and Ca ions. In a single-salt solution with NH, the optimized operating voltage of the hybrid CDI cell was 0.8 V, with a higher salt adsorption capacity (51.2 mg/g) than those obtained at other voltages (0.1, 0.4, 1.2 V). In a multisalt solution containing NH, Na, and Ca ions, the selectivity coefficients of NH/Ca and NH/Na were 9.5 and 4.9, respectively. The feasibility of selective NH capture using the NiHCF electrode in a hybrid CDI cell was demonstrated by treating the effluent from a municipal wastewater treatment plant (WWTP). The intercalation preference of the NiHCF electrode with the WWTP effluent was NH>K>Na>Ca>Mg, and NH showed the highest salt adsorption capacity among the cations during consecutive cycles. Our results revealed that cations with smaller hydrated radii and lower (de)hydration energies were more favorably intercalated by the NiHCF electrode. The results provide important knowledge regarding the use of intercalation-type electrodes for selective nutrient removal and recovery from wastewater.