Zhu Jia-Xian, Wang Xiao-Qi, Ou Sheng-Ju, Zhang Xin-Yu
Key Laboratory of Beijing on Regional Air Pollution Control, Faculty of Environmental and Life, Beijing University of Technology, Beijing 100124, China.
Huan Jing Ke Xue. 2022 Jul 8;43(7):3473-3482. doi: 10.13227/j.hjkx.202110085.
The pollution characteristics of surface ozone and its response to meteorological factors were studied based on monitoring in July 2019 in Shijiazhuang City, China. Furthermore, the WRF-CMAQ model coupled with O isopleths (EKMA curves) were applied to explore the non-linear response relationship of O to precursors VOCs and NO, aiming to identify a suitable precursor control strategy. The results showed that the days with the maximum daily 8-hour average ozone concentration (MDA8 O) exceeded the standard by 70.9%. The nonattainment days were usually accompanied by higher temperature, lower relative humidity, and low winds, and the south and southeast winds occurred frequently. The O formation was in the strong VOC-limited regime in the urban area of Shijiazhuang, whereas it was in the NO and VOCs transition regime in suburban areas. As for the urban area, under the condition of single NO emission reduction, O pollution improved when continuous NO emission reduction was higher than 50% during the nonattainment days. By contrast, during the non-polluted days, O concentrations would not rebound when the reduction ratio of NO and VOCs was higher than 1. In conclusion, VOCs reduction should be the priority for emission reduction plans in urban areas, whereas all different NO and VOCs ratios led to a decline in O concentration in the suburban areas, and a VOCs:NO of 1:2 was recommended.
基于2019年7月在中国石家庄市的监测,研究了地表臭氧的污染特征及其对气象因素的响应。此外,应用WRF-CMAQ模型结合臭氧等值线(EKMA曲线)来探讨臭氧对前体物挥发性有机物(VOCs)和氮氧化物(NO)的非线性响应关系,旨在确定合适的前体物控制策略。结果表明,日最大8小时平均臭氧浓度(MDA8 O₃)超标天数占70.9%。超标日通常伴随着较高温度、较低相对湿度和小风,且南风和东南风频繁出现。石家庄市城区臭氧生成处于强VOCs限制区,而郊区处于NO和VOCs过渡区。对于城区,在单因子减排NO的情况下,超标日持续减排NO高于50%时,臭氧污染有所改善。相比之下,在非污染日,NO和VOCs减排比例高于1时,臭氧浓度不会反弹。综上所述,城区减排计划应优先考虑减排VOCs,而在郊区,不同的NO和VOCs比例均导致臭氧浓度下降,建议VOCs:NO为1:2。