Khan Abdul Ahad, Gul Jawad, Naqvi Salman Raza, Ali Imtiaz, Farooq Wasif, Liaqat Rabia, AlMohamadi Hamad, Štěpanec Libor, Juchelková Dagmar
School of Chemical and Materials Engineering, National University of Science & Technology, H-12, Islamabad, Pakistan.
School of Chemical and Materials Engineering, National University of Science & Technology, H-12, Islamabad, Pakistan.
Chemosphere. 2022 Nov;306:135565. doi: 10.1016/j.chemosphere.2022.135565. Epub 2022 Jul 3.
Textile industry utilize a massive amount of dyes for coloring. The dye-containing effluent is released into wastewater along with heavy metals that are part of dye structure. The treatment of textile industry wastewater using conventional techniques (coagulation, membrane technique, electrolysis ion exchange, etc.) is uneconomical and less efficient (for a low concentration of pollutants). Moreover, most of these techniques produce toxic sludge, making them less environmentally friendly. Algae base industry is growing for food, cosmetics and energy needs. Algae biomass in unique compared to lignocellulosic biomass due to presence of various functional group on its surface and presence of various cations. These two characteristics are unique for biochar as a tool for environmental decontamination. Algae biomass contain functional groups and cations that can be effective for removal of organic contaminants (dyes) and heavy metals. Algae can be micro and macro and both have entirely different biomass composition which will lead to a synthesis of different biochar even under same synthesis process. This study reviews the recent progress in the development of an economically viable and eco-friendly approach for textile industry wastewater using algae biomass-derived absorbents. The strategy employed microalgal biochar to remove organic pollutants (dyes) and heavy metals from textile effluents by biosorption. This article discusses different methods for preparing algal biochar (pyrolysis, hydrothermal carbonization and torrefaction), and the adsorption capacity of biochar for dyes and heavy metals. Work on hydrothermal carbonization and torrefaction of microalgal biomass for biochar is limited. Variation in structural and functional groups changes on biochar compared to original microalgal biomass are profound in contract with lignocellulosic biomass. Existing Challenges, future goals, and the development of these technologies at the pilot level are also discussed.
纺织工业使用大量染料进行染色。含有染料的废水与作为染料结构一部分的重金属一起排放到废水中。使用传统技术(混凝、膜技术、电解离子交换等)处理纺织工业废水既不经济效率又低(对于低浓度污染物而言)。此外,这些技术大多会产生有毒污泥,使其对环境不太友好。藻类产业因食品、化妆品和能源需求而不断发展。与木质纤维素生物质相比,藻类生物质具有独特性,因为其表面存在各种官能团以及各种阳离子。这两个特性使生物炭成为一种环境净化工具。藻类生物质含有可有效去除有机污染物(染料)和重金属的官能团和阳离子。藻类可分为微藻和宏藻,两者的生物质组成完全不同,即使在相同的合成过程下也会导致合成不同的生物炭。本研究综述了利用藻类生物质衍生吸附剂处理纺织工业废水的经济可行且环保方法的最新进展。该策略采用微藻生物炭通过生物吸附去除纺织废水中的有机污染物(染料)和重金属。本文讨论了制备藻类生物炭的不同方法(热解、水热碳化和烘焙),以及生物炭对染料和重金属的吸附能力。关于微藻生物质水热碳化和烘焙制备生物炭的研究有限。与原始微藻生物质相比,生物炭结构和官能团的变化与木质纤维素生物质相比有很大不同。还讨论了现有挑战、未来目标以及这些技术在中试规模的发展情况。