Samanta Apurba, Pramanik Shyamal, Mondal Subhashis, Maity Soumitra
Department of Chemistry and Chemical Biology, Indian Institute of Technology (ISM), Dhanbad, Jharkhand, 826004, India.
Chem Commun (Camb). 2022 Jul 26;58(60):8400-8403. doi: 10.1039/d2cc02574d.
Organic photoredox-catalyzed alkylamination of olefins is performed with alkyl halides and nitrile solvent by blocking the traditional photoredox-ATRA process with Zn(OAc). A range of carbon-centered radicals (α-alkylcarbonyl, benzyl, cyanomethyl) are effectively participating in this strategy giving rise to versatile carboamination products with high synthetic value.
通过用乙酸锌阻断传统的光氧化还原-原子转移自由基加成（ATRA）过程，在卤代烃和腈类溶剂存在下进行有机光氧化还原催化的烯烃烷基胺化反应。一系列碳中心自由基（α-烷基羰基、苄基、氰甲基）有效地参与了该策略，从而得到具有高合成价值的多种碳胺化产物。
