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锑碲( = 钬和铽)中的竞争磁相。

Competing Magnetic Phases in SbTe ( = Ho and Tb).

作者信息

Plokhikh Igor, Pomjakushin Vladimir, Gawryluk Dariusz Jakub, Zaharko Oksana, Pomjakushina Ekaterina

机构信息

Laboratory for Multiscale Materials Experiments, Paul Scherrer Institut, PSI, Villigen CH-5232, Switzerland.

Laboratory for Neutron Scattering and Imaging (LNS), Paul Scherrer Institut, PSI, Villigen CH-5232, Switzerland.

出版信息

Inorg Chem. 2022 Jul 25;61(29):11399-11409. doi: 10.1021/acs.inorgchem.2c01711. Epub 2022 Jul 7.

Abstract

The interplay between a topological electronic structure and magnetism may result in intricate physics. In this work, we describe a case of rather peculiar coexistence or competition of several magnetic phases below seemingly single antiferromagnetic transition in SbTe ( = Ho and Tb) topological semimetals, the magnetic members of the ZrSiS/PbFCl structure type (space group 4/). Neutron diffraction experiments reveal a complex multi-step order below = 3.8 K ( = Ho) and = 6.4 K ( = Tb). Magnetic phases can be described using four propagation vectors = (/ 0 0) and = (/ 0 /) at a base temperature of 1.7 K, which transform into incommensurate vectors ' = (/ - δ 0 0) and = (/ - δ 0 /) at elevated temperatures in both compounds. Together with the refined models of magnetic structures, we present the group theoretical analysis of magnetic symmetry of the proposed solutions. These results prompt further investigations of the relation between the electronic structure of those semimetals and the determined antiferromagnetic ordering existing therein.

摘要

拓扑电子结构与磁性之间的相互作用可能会导致复杂的物理现象。在这项工作中,我们描述了在 SbTe( = Ho 和 Tb)拓扑半金属中,在看似单一的反铁磁转变温度以下,几种磁相相当奇特的共存或竞争情况,SbTe 是具有 ZrSiS/PbFCl 结构类型(空间群 4/)的磁性成员。中子衍射实验揭示了在 = 3.8 K( = Ho)和 = 6.4 K( = Tb)以下存在复杂的多步有序状态。在 1.7 K 的基温下,磁相可以用四个传播矢量 = (/ 0 0) 和 = (/ 0 /) 来描述,在两种化合物中,在较高温度下它们会转变为非公度矢量 ' = (/ - δ 0 0) 和 = (/ - δ 0 /)。结合磁结构的精确模型,我们对所提出的解决方案的磁对称性进行了群论分析。这些结果促使人们进一步研究那些半金属的电子结构与其中确定的反铁磁有序之间的关系。

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