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过冷液体的局域塑性响应与缓慢非均匀动力学

Local Plastic Response and Slow Heterogeneous Dynamics of Supercooled Liquids.

作者信息

Li Yan-Wei, Yao Yugui, Ciamarra Massimo Pica

机构信息

Key Laboratory of Advanced Optoelectronic Quantum Architecture and Measurement (MOE), School of Physics, Beijing Institute of Technology, Beijing, 100081, China.

Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore, CNR-SPIN, Dipartimento di Scienze Fisiche, Università di Napoli Federico II, I-80126, Napoli, Italy and CNRS@CREATE LTD, 1 Create Way, No. 08-01 CREATE Tower, Singapore 138602, Singapore.

出版信息

Phys Rev Lett. 2022 Jun 24;128(25):258001. doi: 10.1103/PhysRevLett.128.258001.

Abstract

We demonstrate, via numerical simulations, that the relaxation dynamics of supercooled liquids correlates well with a plastic length scale measuring a particle's response to impulsive localized perturbations and weakly to measures of local elasticity. We find that the particle averaged plastic length scale vanishes linearly in temperature and controls the super-Arrhenius temperature dependence of the relaxation time. Furthermore, we show that the plastic length scale of individual particles correlates with their typical displacement at the relaxation time. In contrast, the local elastic response only correlates with the dynamics on the vibrational timescale.

摘要

通过数值模拟,我们证明了过冷液体的弛豫动力学与一个塑性长度尺度密切相关,该尺度衡量了粒子对脉冲局部微扰的响应,而与局部弹性的度量关系较弱。我们发现,粒子平均塑性长度尺度在温度中呈线性消失,并控制着弛豫时间的超阿累尼乌斯温度依赖性。此外,我们表明单个粒子的塑性长度尺度与其在弛豫时间的典型位移相关。相比之下,局部弹性响应仅与振动时间尺度上的动力学相关。

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