2,5-呋喃二甲酸：单体和聚合物合成的有趣前体。
2,5-Furandicarboxylic Acid: An Intriguing Precursor for Monomer and Polymer Synthesis.
机构信息
Institut de Recherche de Chimie Paris, CNRS, Chimie ParisTech, PSL University, 75005 Paris, France.
出版信息
Molecules. 2022 Jun 24;27(13):4071. doi: 10.3390/molecules27134071.
The most versatile furanic building block for chemical and polymer applications is 2,5-furandicarboxylic acid. However, the classical 2,5-furandicarboxylic acid production methodology has been found to have significant drawbacks that hinder industrial-scale production. This review highlights new alternative methods to synthesize 2,5-furandicarboxylic acid that are both more advantageous and attractive than conventional oxidation of 5-hydroxymethylfurfural. This review also focuses on the use of 2,5-furandicarboxylic acid as a polymer precursor and the various potential applications that arise from these furan-based materials.
2,5-呋喃二甲酸是化学和聚合物应用中用途最广泛的糠醛基砌块。然而，经典的 2,5-呋喃二甲酸生产方法存在明显的缺点，阻碍了其在工业规模上的生产。本综述重点介绍了比传统的 5-羟甲基糠醛氧化更为有利和有吸引力的合成 2,5-呋喃二甲酸的新替代方法。本综述还关注了 2,5-呋喃二甲酸作为聚合物前体的用途，以及这些呋喃基材料所带来的各种潜在应用。
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