School of Chemistry, Cardiff University, Park Place, Main Building, CF10 3AT, Cardiff, UK.
ChemistryOpen. 2022 Jul;11(7):e202200145. doi: 10.1002/open.202200145.
New iodotriptycenes, including some chiral derivatives, have been synthesised, and their catalytic potential towards oxidative transformations has been investigated. The enantioselectivities observed in the products using chiral iodotriptycene catalysts are low, probably owing to the large distances between the coordinating groups and the iodine moieties in these compounds.
新的碘三苯并环化合物，包括一些手性衍生物，已经被合成出来，并对其在氧化转化中的催化潜力进行了研究。使用手性碘三苯并环化合物催化剂时，观察到产物的对映选择性较低，这可能是由于这些化合物中配位基团和碘部分之间的距离较大所致。
