通过镍（II）还原法制备的室温稳定的镁电子化物
Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction.
作者信息
Day Craig S, Do Cuong Dat, Odena Carlota, Benet-Buchholz Jordi, Xu Liang, Foroutan-Nejad Cina, Hopmann Kathrin H, Martin Ruben
机构信息
Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007 Tarragona, Spain.
Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, c/Marcel·lí Domingo, 1, 43007 Tarragona, Spain.
出版信息
J Am Chem Soc. 2022 Jul 27;144(29):13109-13117. doi: 10.1021/jacs.2c01807. Epub 2022 Jul 13.
Herein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to their high solubility, modular redox potentials, and formation of insoluble, non-coordinating byproducts. The applicability of these reductants is showcased by accessing low-valent (bipy)Ni(0) species that are challenging to access otherwise.
在此，我们报告了高度还原的联吡啶镁配合物的合成，以及通过量子力学计算和X射线衍射支持的稳定有机镁电子化物的首个实例。这些配合物由于其高溶解性、模块化氧化还原电位以及形成不溶性、非配位副产物，可作为非常规的均相还原剂。通过获得低价态（联吡啶）Ni(0)物种展示了这些还原剂的适用性，否则很难获得这些物种。
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