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用于提高饮料中电化学葡萄糖传感性能的整体纳米花状 MoS@CuCoO 异质结构

An integrated nanoflower-like MoS@CuCoO heterostructure for boosting electrochemical glucose sensing in beverage.

机构信息

College of Food Science and Engineering, Northwest A&F University, Yangling 712100, Shaanxi, China.

College of Food Science and Engineering, Northwest A&F University, Yangling 712100, Shaanxi, China.

出版信息

Food Chem. 2022 Dec 1;396:133630. doi: 10.1016/j.foodchem.2022.133630. Epub 2022 Jul 6.

Abstract

Excessive glucose in food poses a non-negligible threat to its inherent quality and human health, which makes it imperative to develop a highly sensitive sensor for real-time glucose detection. In this work, an integrated electrochemical glucose sensor based on a nanoflower-like MoS@CuCoO heterostructure was carefully constructed. Under optimal conditions, the as-fabricated sensor exhibited a high sensitivity of 1,303 μA mM cm over a wide range of 0.5-393.0 μmol/L, accompanied by a low determination limit (0.5 μmol/L) and short response time (2.1 s). The favorable sensing performance of the MoS@CuCoO nanocomposite-modified electrode in electrochemical analyses was attributed to the introduction of unique nanoflower-like heterostructure and the synergistic effects between MoS and CuCoO. Furthermore, the satisfactory applicability of this sensor in beverages was confirmed. These results demonstrate that the MoS@CuCoO/GCE may be a promising platform for sensitive monitoring of glucose content in food samples.

摘要

食物中过多的葡萄糖对其固有质量和人类健康构成了不可忽视的威胁,这使得开发一种用于实时葡萄糖检测的高灵敏度传感器变得尤为重要。在这项工作中,我们精心构建了一种基于纳米花状 MoS@CuCoO 异质结构的集成电化学葡萄糖传感器。在最佳条件下,所制备的传感器在 0.5-393.0 μmol/L 的较宽范围内表现出 1303 μA mM cm 的高灵敏度,同时具有较低的检测限(0.5 μmol/L)和较短的响应时间(2.1 s)。MoS@CuCoO 纳米复合材料修饰电极在电化学分析中的良好传感性能归因于独特的纳米花状异质结构的引入以及 MoS 和 CuCoO 之间的协同作用。此外,还证实了该传感器在饮料中的令人满意的适用性。这些结果表明,MoS@CuCoO/GCE 可能是一种用于灵敏监测食品样品中葡萄糖含量的有前途的平台。

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