Mohamed Mohamed Gamal, Kuo Shiao-Wei
Department of Materials and Optoelectronic Science, Center for Functional Polymers and Supramolecular Materials, National Sun Yat-Sen University, Kaohsiung 80424, Taiwan.
Soft Matter. 2022 Aug 3;18(30):5535-5561. doi: 10.1039/d2sm00635a.
This Review describes recent progress in the self-assembly of organic/inorganic POSS hybrids derived from mono-, di-, and multi-functionalized POSS cages. We highlight the self-assembled structures and physical properties of giant surfactants and chain-end- and side-chain-type hybrids derived from mono-functionalized POSS cages; main-chain-type hybrids derived from di-functionalized POSS cages; and star-shaped hybrids derived from multi-functionalized POSS cages; with various polymeric attachments, including polystyrene, poly(methyl methacrylate), phenolic, PVPh, and polypeptides.
本综述描述了源自单官能化、双官能化和多官能化倍半硅氧烷笼的有机/无机倍半硅氧烷杂化物自组装的最新进展。我们重点介绍了源自单官能化倍半硅氧烷笼的巨型表面活性剂、链端型和侧链型杂化物；源自双官能化倍半硅氧烷笼的主链型杂化物；以及源自多官能化倍半硅氧烷笼的星形杂化物的自组装结构和物理性质；这些杂化物带有各种聚合物连接基团，包括聚苯乙烯、聚甲基丙烯酸甲酯、酚类、聚乙烯基苯酚和多肽。
