Zare Yasser, Rhee Kyong-Yop, Park Soo-Jin
Biomaterials and Tissue Engineering Research Group, Department of Interdisciplinary Technologies, Breast Cancer Research Center, Motamed Cancer Institute, ACECR, Tehran 1125342432, Iran.
Department of Mechanical Engineering (BK21 Four), College of Engineering, Kyung Hee University, Yongin 17104, Korea.
Nanomaterials (Basel). 2022 Jul 12;12(14):2383. doi: 10.3390/nano12142383.
Interfacial conductivity and "", i.e., the least carbon-nanotube (CNT) length required for the operative transfer of CNT conductivity to the insulated medium, were used to establish the most effective CNT concentration and portion of CNTs needed for a network structure in polymer CNT nanocomposites (PCNT). The mentioned parameters and tunneling effect define the effective conductivity of PCNT. The impact of the parameters on the beginning of percolation, the net concentration, and the effective conductivity of PCNT was investigated and the outputs were explained. Moreover, the calculations of the beginning of percolation and the conductivity demonstrate that the experimental results and the developed equations are in acceptable agreement. A small "" and high interfacial conductivity affect the beginning of percolation, the fraction of networked CNTs, and the effective conductivity. Additionally, a low tunneling resistivity, a wide contact diameter, and small tunnels produce a highly effective conductivity. The developed model can be used to optimize breast cancer cell sensors.
界面电导率以及“”,即碳纳米管(CNT)电导率有效转移至绝缘介质所需的最短碳纳米管长度,被用于确定聚合物碳纳米管纳米复合材料(PCNT)中形成网络结构所需的最有效碳纳米管浓度及碳纳米管比例。上述参数和隧穿效应决定了PCNT的有效电导率。研究了这些参数对PCNT渗流起始、净浓度和有效电导率的影响,并对结果进行了解释。此外,渗流起始和电导率的计算表明,实验结果与所推导的方程吻合良好。较小的“”和较高的界面电导率会影响渗流起始、网络化碳纳米管的比例以及有效电导率。此外,较低的隧穿电阻率、较宽的接触直径和较小的隧道会产生高效的电导率。所开发的模型可用于优化乳腺癌细胞传感器。