Song Xiaohui, Chen Mingxiang, Zhang Jingshuang, Zhang Rui, Zhang Wei
Institute of Applied Physics, Henan Academy of Science, Zhengzhou 450008, China.
School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
Nanomaterials (Basel). 2022 Jul 20;12(14):2483. doi: 10.3390/nano12142483.
Graphene-copper nanolayered composites have received research interest as promising packaging materials in developing next-generation electronic and optoelectronic devices. The weak van der Waal (vdW) contact between graphene and metal matrix significantly reduces the mechanical performance of such composites. The current study describes a new Cu-nanoporous graphene-Cu based bonding method with a low bonding temperature and good dependability. The deposition of copper atoms onto nanoporous graphene can help to generate nanoislands on the graphene surface, facilitating atomic diffusion bonding to bulk copper bonding surfaces at low temperatures, according to our extensive molecular dynamics (MD) simulations on the bonding process and pull-out verification using the canonical ensemble (NVT). Furthermore, the interfacial mechanical characteristics of graphene/Cu nanocomposites can be greatly improved by the resistance of nanostructure in nanoporous graphene. These findings are useful in designing advanced metallic surface bonding processes and graphene-based composites with tenable performance.
石墨烯-铜纳米层状复合材料作为下一代电子和光电器件中有前景的封装材料受到了研究关注。石墨烯与金属基体之间较弱的范德华(vdW)接触显著降低了此类复合材料的机械性能。当前研究描述了一种新的基于铜-纳米多孔石墨烯-铜的键合方法,该方法具有低键合温度和良好的可靠性。根据我们对键合过程的广泛分子动力学(MD)模拟以及使用正则系综(NVT)的拔出验证,铜原子沉积到纳米多孔石墨烯上有助于在石墨烯表面生成纳米岛,从而在低温下促进原子扩散键合到块状铜键合表面。此外,纳米多孔石墨烯中纳米结构的阻力可极大地改善石墨烯/铜纳米复合材料的界面力学特性。这些发现有助于设计具有稳定性能的先进金属表面键合工艺和基于石墨烯的复合材料。