Biosorption Potential of Microbial and Residual Biomass of Immobilized in Calcium Alginate Matrix for Pharmaceuticals Removal from Aqueous Solutions.

Two types of biosorbents, based on immobilized in calcium alginate, were studied for the removal of pharmaceuticals from aqueous solutions. Synthetized biocomposite materials were characterized chemically and morphologically, both before and after simulated biosorption. Ethacridine lactate (EL) was chosen as a target molecule. The process performance was interpreted as a function of initial solution pH, biosorbent dose, and initial pharmaceutical concentration. The results exhibited that the removal efficiencies were superior to 90% for both biosorbents, at the initial pH value of 4.0 and biosorbent dose of 2 g/L for all EL initial concentrations tested. Freundlich, Temkin, Hill, Redlich-Peterson, Sips, and Toth isotherms were used to describe the experimental results. The kinetic data were analyzed using kinetic models, such as pseudo-first order, pseudo-second order, Elovich, and Avrami, to determine the kinetic parameters and describe the transport mechanisms of EL from aqueous solution onto biosorbents. Among the tested equations, the best fit is ensured by the pseudo-second-order kinetics model for both biosorbents, with the correlation coefficient having values higher than 0.996. The many potential advantages and good biosorptive capacity of biomass immobilized in calcium alginate recommend these types of biocomposite materials for the removal of pharmaceuticals from aqueous solutions.