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利用野生扁桃()籽油通过多相催化剂生产生物柴油。

Biodiesel Production Using Wild Apricot () Seed Oil via Heterogeneous Catalysts.

机构信息

Department of Plant Sciences, Quaid-i-Azam University, Islamabad 45320, Pakistan.

CAS Key Laboratory of Mountain Ecological Restoration and Bioresource Utilization, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, China.

出版信息

Molecules. 2022 Jul 25;27(15):4752. doi: 10.3390/molecules27154752.

Abstract

We confined the formation and characterization of heterogenous nano-catalysts and then used them to produce biodiesel from the novel non-edible seed oil of . seeds' oil content was extracted at about 52.4 ± 3% with 0.77% FFA. Three different heterogenous nano-catalysts-calcined (CPC), KPC, and KOH-activated cake Titanium Dioxide (TiO)-were synthesized using calcination and precipitation methods. The mentioned catalysts were characterized through XRD, SEM, and EDX to inspect their crystallin dimension, shape, and arrangement. Titanium dioxide has morphological dimensions so that the average particle size ranges from 49-60 nm. The result shows that the crystal structure of TiO is tetragonal (Anatase). The surface morphology of CPC illustrated that the roughness of the surface was increased after calcination, many macropores and hollow cavities appeared, and the external structure became very porous. These changes in morphology may increase the catalytic efficiency of CPC than non-calcined oil cake. The fuel belonging to PAOB stood according to the series suggested by ASTM criteria. All the characterization reports that is a novel and efficient potential source of biodiesel as a green energy source.

摘要

我们限制了异质纳米催化剂的形成和特性研究,然后使用它们从 种子的新型非食用籽油中生产生物柴油。 种子的油含量约为 52.4±3%,游离脂肪酸含量为 0.77%。使用煅烧和沉淀法合成了三种不同的异质纳米催化剂-煅烧的(CPC)、KPC 和 KOH 活化 饼二氧化钛(TiO)。通过 XRD、SEM 和 EDX 对所述催化剂进行了表征,以检查其结晶尺寸、形状和排列。二氧化钛具有形态尺寸,因此平均粒径范围为 49-60nm。结果表明,TiO 的晶体结构为四方晶系(锐钛矿)。CPC 的表面形态表明,煅烧后表面粗糙度增加,出现许多大孔和空心腔,外部结构变得非常多孔。这种形态的变化可能会提高 CPC 比未经煅烧的 油饼的催化效率。根据 ASTM 标准建议的系列,燃料属于 PAOB。所有的特性研究表明, 是生物柴油的新型有效潜在来源,是一种绿色能源。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b32e/9332148/05931f37ab74/molecules-27-04752-g001.jpg

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