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杏仁直接转化为生物柴油。

Direct conversion of apricot seeds into biodiesel.

机构信息

Department of Earth Resources and Environmental Engineering, Hanyang University, Seoul 04763, Republic of Korea.

Department of Environmental Engineering, Kyungpook National University, Daegu 41566, Republic of Korea.

出版信息

Bioresour Technol. 2024 Mar;395:130339. doi: 10.1016/j.biortech.2024.130339. Epub 2024 Jan 18.

Abstract

Using edible lipids for biodiesel production has been criticized, causing biodiesel production from inedible food resources to be desirable. Lipid extraction must be prioritized to produce biodiesel using an acid/base-catalyzed transesterification process, but this conversion process suffers from technical reliability. Therefore, this study introduced non-catalytic conversion of oil-bearing biomass into biodiesel. Apricot seeds were used as a model compound (oil content 44.3 wt%). The non-catalytic transesterification of apricot seed oil recovered 98.28 wt% biodiesel at 360 °C for 1 min, while alkali-catalysis of apricot seed oil recovered 91.84 wt% at 63 °C for 60 min. The direct conversion of apricot seeds into biodiesel was attempted. The trends in the yields of biodiesel from apricot seeds and seed oil obtained by non-catalytic transesterification as a function of reaction temperature were similar. The yield of biodiesel from apricot seed was 43.06 wt%, suggesting that 97.20 wt% of lipids were converted into biodiesel.

摘要

使用可食用油脂生产生物柴油一直受到批评,因此人们希望利用不可食用的食物资源来生产生物柴油。为了利用酸碱催化的酯交换法生产生物柴油,必须优先进行油脂提取,但这种转化过程存在技术可靠性问题。因此,本研究介绍了利用含油生物质进行非催化转化生产生物柴油的方法。以杏仁为模型化合物(油含量为 44.3wt%)。在 360°C 下,杏仁油的非催化酯交换反应 1 分钟即可回收 98.28wt%的生物柴油,而杏仁油的碱催化反应在 63°C 下 60 分钟可回收 91.84wt%的生物柴油。此外,还尝试了直接将杏仁转化为生物柴油。非催化酯交换反应中,杏仁及其油转化为生物柴油的产率随反应温度的变化趋势相似。杏仁的生物柴油产率为 43.06wt%,表明 97.20wt%的油脂转化为生物柴油。

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