Efficient Catalytic Conversion of Glucose into Lactic Acid over Y-β and Yb-β Zeolites.

In this work, a new type of modified β zeolites with rare earth elements (ree) was discovered for producing lactic acid from glucose and achieved a good catalytic effect. At first, the catalytic performances of ree-β zeolites, ree oxides, and single-transition-metal-β zeolites were compared, and the result showed that Y-β and Yb-β zeolites had the best catalytic activity under the same reaction conditions. Under the best reaction conditions, the maximum yields of lactic acid with Y-β and Yb-β catalysts were 45.3 and 43.6%, respectively. The acid characterization showed that Y/Yb-β zeolites had a similar number of Lewis acid sites as Sn-β zeolites, and they were also more than other transition-metal-β zeolites. Thus, Y-β and Yb-β zeolites had a higher lactic acid yield than those catalysts. It is interesting to note that Y-β and Yb-β zeolites owned more Brønsted acids but produced fewer byproducts. Combining the decomposition experiment of 5-hydroxymethyl furfural, fewer byproducts were produced with Y-β and Yb-β zeolites because the low amount of Brønsted acid contained could hinder the decomposition of 5-hydroxymethyl furfural, thereby slowing down the side reaction.