Rathee Vikram, Miller Joia, Blair Daniel L, Urbach Jeffrey S
Department of Physics and Institute for Soft Matter Synthesis and Metrology, Georgetown University, Washington, DC 20057.
Proc Natl Acad Sci U S A. 2022 Aug 9;119(32):e2203795119. doi: 10.1073/pnas.2203795119. Epub 2022 Aug 1.
We report direct measurements of spatially resolved stress at the boundary of a shear-thickening cornstarch suspension revealing persistent regions of high local stress propagating in the flow direction at the speed of the top boundary. The persistence of these propagating fronts enables precise measurements of their structure, including the profile of boundary stress measured by boundary stress microscopy (BSM) and the nonaffine velocity of particles at the bottom boundary of the suspension measured by particle image velocimetry (PIV). In addition, we directly measure the relative flow between the particle phase and the suspending fluid (fluid migration) and find the migration is highly localized to the fronts and changes direction across the front, indicating that the fronts are composed of a localized region of high dilatant pressure and low particle concentration. The magnitude of the flow indicates that the pore pressure difference driving the fluid migration is comparable to the critical shear stress for the onset of shear thickening. The propagating fronts fully account for the increase in viscosity with applied stress reported by the rheometer and are consistent with the existence of a stable jammed region in contact with one boundary of the system that generates a propagating network of percolated frictional contacts spanning the gap between the rheometer plates and producing strong localized dilatant pressure.
我们报告了对剪切增稠玉米淀粉悬浮液边界处空间分辨应力的直接测量结果,揭示了高局部应力的持续区域以顶部边界的速度沿流动方向传播。这些传播前沿的持续性使得能够精确测量其结构,包括通过边界应力显微镜(BSM)测量的边界应力分布以及通过粒子图像测速技术(PIV)测量的悬浮液底部边界处粒子的非仿射速度。此外,我们直接测量了颗粒相和悬浮流体之间的相对流动(流体迁移),发现迁移高度局限于前沿并且在前沿处改变方向,这表明前沿由高剪胀压力和低颗粒浓度的局部区域组成。流动的大小表明驱动流体迁移的孔隙压力差与剪切增稠开始时的临界剪切应力相当。传播前沿完全解释了流变仪所报告的粘度随施加应力的增加,并且与系统一个边界处存在稳定的堵塞区域一致,该区域产生了一个贯穿流变仪板之间间隙的渗透摩擦接触传播网络,并产生强烈的局部剪胀压力。