Lilin Paul, Elkhoury Jean E, Peters Ivo R, Bischofberger Irmgard
Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
Schlumberger-Doll Research, Cambridge, MA 02139, USA.
PNAS Nexus. 2023 Dec 22;3(1):pgad451. doi: 10.1093/pnasnexus/pgad451. eCollection 2024 Jan.
Dense suspensions exhibit the remarkable ability to switch dynamically and reversibly from a fluid-like to a solid-like, shear-jammed (SJ) state. Here, we show how this transition has important implications for the propensity for forming fractures. We inject air into bulk dense cornstarch suspensions and visualize the air invasion into the opaque material using time-resolved X-ray radiography. For suspensions with cornstarch mass fractions high enough to exhibit discontinuous shear thickening and shear jamming, we show that air injection leads to fractures in the material. For high mass fractions, these fractures grow quasistatically as rough cavities with fractured interfaces. For lower mass fractions, remarkably, the fractures can relax to smooth bubbles that then rise under buoyancy. We show that the onset of the relaxation occurs as the shear rate induced by the air cavity growth decreases below the critical shear rate denoting the onset of discontinuous shear thickening, which reveals a structural signature of the SJ state.
浓稠悬浮液展现出显著的能力,能够动态且可逆地从类似流体的状态转变为类似固体的、剪切堵塞(SJ)状态。在此,我们展示了这种转变如何对形成裂缝的倾向产生重要影响。我们将空气注入大量浓稠的玉米淀粉悬浮液中,并使用时间分辨X射线成像技术来观察空气侵入这种不透明材料的过程。对于玉米淀粉质量分数高到足以表现出不连续剪切增稠和剪切堵塞的悬浮液,我们发现注入空气会导致材料中出现裂缝。对于高质量分数的情况,这些裂缝会以具有断裂界面的粗糙空洞的形式准静态地扩展。值得注意的是,对于较低质量分数的情况,裂缝会松弛为光滑的气泡,然后在浮力作用下上升。我们表明,松弛的开始发生在由气腔生长引起的剪切速率降低到低于表示不连续剪切增稠开始的临界剪切速率时,这揭示了SJ状态的一种结构特征。