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研究不同分子量聚偏氟乙烯(PVDF)聚合物在编织中空纤维膜制备和性能方面的应用。

Investigation of different molecular weight Polyvinylidene Fluoride (PVDF) polymer for the fabrication and performance of braid hollow fiber membranes.

作者信息

Tuncay Gizem, Türken Türker, Koyuncu İsmail

机构信息

National Research Center on Membrane Technologies, Istanbul Technical University, Istanbul, Turkey.

Department of Environmental Engineering, Istanbul Technical University Istanbul, Turkey.

出版信息

Environ Technol. 2024 Jan;45(3):404-417. doi: 10.1080/09593330.2022.2112092. Epub 2022 Aug 22.

Abstract

In the current study, braid reinforced membranes were fabricated from polyvinylidene fluoride (PVDF) polymers with two different molecular weights, and the blending of the polymers in a 1:1 ratio to upgrade the performance of the membrane. Characterization, filtration studies, and membrane bioreactor (MBR) application were done to evaluate membrane performance by applying the same operation conditions on each membrane. Characterization studies indicated that the fabricated membrane from blending polymers was a hydrophilic structure with a contact angle of 50.78° and smoother surface properties compared to the other fabricated membranes. According to the MBR results, at the end of the operation process, TMP levels of the membrane from the blending method are found 150 mbar, membrane from high molecular weight PVDF polymer had 250 mbar, and membrane from low molecular weight PVDF polymer had 800 mbar. As a consequence of the investigation, it is seen that the hydrophilic structure of the membrane allows the pollutant to adsorb less to the blend membrane surface, and the lower roughness is also a factor in reducing fouling.

摘要

在本研究中,辫状增强膜由两种不同分子量的聚偏二氟乙烯(PVDF)聚合物制成,并以 1:1 的比例混合聚合物以提高膜的性能。通过在每个膜上应用相同的操作条件,进行了表征、过滤研究和膜生物反应器(MBR)应用,以评估膜性能。表征研究表明,与其他制备的膜相比,由共混聚合物制备的膜具有亲水性结构,接触角为 50.78°,表面性质更光滑。根据 MBR 结果,在操作过程结束时,发现共混法制备的膜的 TMP 水平为 150 mbar,高分子量 PVDF 聚合物制备的膜为 250 mbar,低分子量 PVDF 聚合物制备的膜为 800 mbar。通过研究可以看出,膜的亲水结构使污染物较少地吸附在共混膜表面,较低的粗糙度也是减少污染的因素。

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