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填料含量和碱处理对棕榈仁饼填料增强环氧复合材料力学性能的影响。

The Influence of Filler Loading and Alkaline Treatment on the Mechanical Properties of Palm Kernel Cake Filler Reinforced Epoxy Composites.

作者信息

Cionita Tezara, Siregar Januar Parlaungan, Shing Wong Ling, Hee Cheng Wan, Fitriyana Deni Fajar, Jaafar Jamiluddin, Junid Ramli, Irawan Agustinus Purna, Hadi Agung Efriyo

机构信息

Faculty of Engineering and Quantity Surveying, INTI International University, Nilai 71800, Negeri Sembilan, Malaysia.

College of Engineering, Universiti Malaysia Pahang, Gambang 26300, Pahang, Malaysia.

出版信息

Polymers (Basel). 2022 Jul 28;14(15):3063. doi: 10.3390/polym14153063.

Abstract

The manufacturing of materials, in conjunction with green technology, emphasises the need to employ renewable resources to ensure long-term sustainability. Re-exploring renewable elements that can be employed as reinforcing materials in polymer composites has been a major endeavour. The research goal is to determine how well palm kernel cake filler (PKCF) performs in reinforced epoxy composites. In this study, PKCF with 100 mesh was mixed with epoxy resin (ER) in various ratios ranging from 10% to 40% by weight. Hand lay-up with an open mould is proposed as a method for fabricating the specimen test. Surface modification of PKCF with varying concentrations of NaOH (5 wt.% and 10 wt.%) will be contrasted with the untreated samples. Using Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC), the effect of alkaline treatment will be examined. The tensile and maximum flexural strength of the untreated PKCF/ER composite were determined in this work, with a 30 wt.% of PKCF having the highest tensile strength of 31.20 MPa and the highest flexural strength of 39.70 MPa. The tensile and flexural strength were reduced to 22.90 MPa and 30.50 MPa, respectively, when the filler loading was raised to 40 wt.%. A 5 wt.% alkali treatment for 1 h improved the composites' mechanical characteristics. Lastly, an alkali treatment can aid in the resolution of the problem of inadequate matrix and filler interaction. Alkaline treatment is a popular and effective method for reducing the hydroxyl group in fillers and, thus, improving interfacial bonding. Overall, palm kernel cake is a promising material used as a filler in polymer composites.

摘要

材料制造与绿色技术相结合,强调了使用可再生资源以确保长期可持续性的必要性。重新探索可作为聚合物复合材料增强材料的可再生元素一直是一项重要工作。研究目标是确定棕榈仁饼填料(PKCF)在增强环氧复合材料中的性能表现。在本研究中,将100目的PKCF与环氧树脂(ER)按重量比10%至40%的不同比例混合。建议采用开放式模具手糊法来制备试样测试。将不同浓度NaOH(5 wt.%和10 wt.%)对PKCF进行表面改性的情况与未处理样品进行对比。使用傅里叶变换红外光谱(FTIR)、热重分析(TGA)和差示扫描量热法(DSC)来研究碱处理的效果。在这项工作中测定了未处理的PKCF/ER复合材料的拉伸强度和最大弯曲强度,当PKCF含量为30 wt.%时,拉伸强度最高,为31.20 MPa,弯曲强度最高,为39.70 MPa。当填料含量提高到40 wt.%时,拉伸强度和弯曲强度分别降至22.90 MPa和30.50 MPa。5 wt.%的碱处理1小时改善了复合材料的力学性能。最后,碱处理有助于解决基体与填料相互作用不足的问题。碱处理是一种常用且有效的方法,可减少填料中的羟基,从而改善界面结合。总体而言,棕榈仁饼是一种有前途的聚合物复合材料填料材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b5a/9370578/5694bcab47c7/polymers-14-03063-g001.jpg

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