Ramakrishnan Rohith K, Silvestri Daniele, Sumitha Nechikkottil S, Nguyen Nhung H A, Havlíček Karel, Łukowiec Dariusz, Wacławek Stanisław, Černík Miroslav, Tiwari Diwakar, Padil Vinod V T, Varma Rajender S
Institute for Nanomaterials, Advanced Technologies and Innovation (C × I), Technical University of Liberec (TUL), Studentská 1402/2, 461 17 Liberec, Czech Republic.
Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology, Kochi 682 022, Kerala, India.
Polymers (Basel). 2022 Jul 31;14(15):3120. doi: 10.3390/polym14153120.
The accumulation of organic contaminants including dyes in aquatic systems is of significant environmental concern, necessitating the development of affordable and sustainable materials for the treatment/elimination of these hazardous pollutants. Here, a green synthesis strategy has been used to develop a self-assembled gum kondagogu-sodium alginate bioconjugate sponge adorned with silver nanoparticles, for the first time. The properties of the nanocomposite sponge were then analyzed using FTIR, TGA, SEM, and MicroCT. The ensued biobased sponge exhibited hierarchical microstructure, open cellular pores, good shape memory, and mechanical properties. It merges the attributes of an open cellular porous structure with metal nanoparticles and are envisaged to be deployed as a sustainable catalytic system for reducing contaminants in the aqueous environment. This nanocomposite sponge showed enhanced catalytic effectiveness ( values up to 37 min g and 44 min g for methylene blue and 4-nitrophenol, respectively), antibacterial properties, reusability, and biodegradability (65% biodegradation in 28 days).
包括染料在内的有机污染物在水生系统中的积累引起了重大环境问题,因此需要开发经济实惠且可持续的材料来处理/消除这些有害污染物。在此,首次采用绿色合成策略制备了一种装饰有银纳米颗粒的自组装贡达胶-海藻酸钠生物共轭海绵。然后使用傅里叶变换红外光谱(FTIR)、热重分析(TGA)、扫描电子显微镜(SEM)和显微计算机断层扫描(MicroCT)对纳米复合海绵的性能进行了分析。所得的生物基海绵具有分级微观结构、开放的细胞孔、良好的形状记忆和机械性能。它将开放细胞多孔结构的特性与金属纳米颗粒相结合,有望作为一种可持续的催化系统用于减少水环境中的污染物。这种纳米复合海绵表现出增强的催化效果(亚甲基蓝和4-硝基苯酚的催化值分别高达37分钟/克和44分钟/克)、抗菌性能、可重复使用性和生物降解性(28天内65%的生物降解率)。