电化学位点选择性的联苯与（硫代）呫吨的烷基化反应。
Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes.
机构信息
Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, School of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, China.
Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, China.
出版信息
Molecules. 2022 Aug 4;27(15):4967. doi: 10.3390/molecules27154967.
Herein, we first report an electrochemical methodology for the site-selective alkylation of azobenzenes with (thio)xanthenes in the absence of any transition metal catalyst or external oxidant. A variety of groups are compatible with this electrochemical alkylation, which furnishes the products in moderate to good yields.
在此，我们首次报道了一种在无任何过渡金属催化剂或外加氧化剂存在下，通过电化学方法实现对偶氮苯的（硫）蒽的位点选择性烷基化的方法。各种基团都与这种电化学烷基化反应兼容，该反应以中等至良好的收率提供产物。
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