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尾巴并非总是关键所在：由Co(NCS)与1,4-双（-烷氧基）-2,5-双（3,2':6',3″-三联吡啶-4'-基）苯配体组装而成的网状结构

A Tail Does Not Always Make a Difference: Assembly of Nets from Co(NCS) and 1,4-bis(-Alkyloxy)-2,5-bis(3,2':6',3″-terpyridin-4'-yl)benzene Ligands.

作者信息

Capomolla Simona S, Manfroni Giacomo, Prescimone Alessandro, Constable Edwin C, Housecroft Catherine E

机构信息

Department of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, Switzerland.

出版信息

Molecules. 2022 Aug 5;27(15):4995. doi: 10.3390/molecules27154995.

DOI:10.3390/molecules27154995
PMID:35956944
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9370426/
Abstract

The consistent assembly of a (6.8) net is observed in reactions of cobalt(II) thiocyanate with 1,4-bis(-alkyloxy)-2,5-bis(3,2':6',3″-terpyridin-4'-yl)benzene ligands in which the alkyloxy substituents are -propyl (ligand ), -butyl (), -pentyl (), -hexyl (), -heptyl (), and -octyl (). Crystals were grown by layering a methanol solution of Co(NCS) over a 1,2-dichlorobenzene solution of each ligand. The choice of crystallization solvents is critical in directing the assembly of the net. Single-crystal structures of [Co(NCS)()]3.5CHCl, [Co(NCS)()]5.5CHCl, [Co(NCS)()]4CHCl, [Co(NCS)()]3.8CHCl, [Co(NCS)()]3.1CHCl, and [Co(NCS)()]1.6CHCl2MeOH (CHCl = 1,2-dichlorobenzene) are presented and compared. The alkyloxy chains exhibit close to extended conformations and are accommodated in cavities in the lattice without perturbation of the coordination framework.

摘要

在钴（II）硫氰酸盐与1,4 - 双（-烷氧基）-2,5 - 双（3,2':6',3″-三联吡啶-4'-基）苯配体的反应中观察到（6.8）网络的一致组装，其中烷氧基取代基为-丙基（配体 ）、-丁基（ ）、-戊基（ ）、-己基（ ）、-庚基（ ）和-辛基（ ）。通过将Co（NCS）的甲醇溶液分层在每种配体的1,2 - 二氯苯溶液上生长晶体。结晶溶剂的选择对于引导网络的组装至关重要。给出并比较了[Co（NCS）（ ）]3.5CHCl、[Co（NCS）（ ）]5.5CHCl、[Co（NCS）（ ）]4CHCl、[Co（NCS）（ ）]3.8CHCl、[Co（NCS）（ ）]3.1CHCl和[Co（NCS）（ ）]1.6CHCl2MeOH（CHCl = 1,2 - 二氯苯）的单晶结构。烷氧基链呈现接近伸展的构象，并容纳在晶格的空腔中而不干扰配位框架。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/032778406a63/molecules-27-04995-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/21ce391298c1/molecules-27-04995-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/39f5435fc755/molecules-27-04995-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/53b4e99595a1/molecules-27-04995-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/488c703c14ca/molecules-27-04995-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/f4c6cca8ecd9/molecules-27-04995-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/cf6cbd581e02/molecules-27-04995-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/3ecc6b3033e2/molecules-27-04995-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/032778406a63/molecules-27-04995-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/21ce391298c1/molecules-27-04995-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/39f5435fc755/molecules-27-04995-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/53b4e99595a1/molecules-27-04995-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/488c703c14ca/molecules-27-04995-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/f4c6cca8ecd9/molecules-27-04995-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/cf6cbd581e02/molecules-27-04995-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/3ecc6b3033e2/molecules-27-04995-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a04b/9370426/032778406a63/molecules-27-04995-g005.jpg

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本文引用的文献

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CrystEngComm. 2022 Jul 7;24(28):5170. doi: 10.1039/d2ce90094g. eCollection 2022 Jul 18.
2
Directing 2D-Coordination Networks: Combined Effects of a Conformationally Flexible 3,2':6',3″-Terpyridine and Chain Length Variation in 4'-(4--Alkyloxyphenyl) Substituents.指导二维配位网络：构象柔性 3,2':6',3″-三联吡啶与 4'-(4--烷氧基苯基)取代基链长变化的综合影响。
Molecules. 2020 Apr 4;25(7):1663. doi: 10.3390/molecules25071663.
3
: from visualization to analysis, design and prediction.
从可视化到分析、设计与预测。
J Appl Crystallogr. 2020 Feb 1;53(Pt 1):226-235. doi: 10.1107/S1600576719014092.
4
A 4'-(4-carboxyphenyl)-3,2':6',3''-terpyridine-based luminescent cadmium(II) coordination polymer for the detection of 2,4,6-trinitrophenol.一种基于4'-(4-羧基苯基)-3,2':6',3''-三联吡啶的发光镉(II)配位聚合物用于检测2,4,6-三硝基苯酚。
Acta Crystallogr C Struct Chem. 2019 May 1;75(Pt 5):508-513. doi: 10.1107/S2053229619004248. Epub 2019 Apr 8.
5
Sometimes the Same, Sometimes Different: Understanding Self-Assembly Algorithms in Coordination Networks.有时相同，有时不同：理解配位网络中的自组装算法
Polymers (Basel). 2018 Dec 11;10(12):1369. doi: 10.3390/polym10121369.
6
4,2':6',4"- and 3,2':6',3"-Terpyridines: The Conflict between Well-Defined Vectorial Properties and Serendipity in the Assembly of 1D-, 2D- and 3D-Architectures.4,2':6',4"-和3,2':6',3"-三联吡啶：一维、二维和三维结构组装中明确的矢量性质与意外发现之间的冲突
Materials (Basel). 2017 Jun 30;10(7):728. doi: 10.3390/ma10070728.
7
The Cambridge Structural Database.剑桥结构数据库。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Apr;72(Pt 2):171-9. doi: 10.1107/S2052520616003954. Epub 2016 Apr 1.
8
Crystal structure refinement with SHELXL.使用SHELXL进行晶体结构精修。
Acta Crystallogr C Struct Chem. 2015 Jan;71(Pt 1):3-8. doi: 10.1107/S2053229614024218. Epub 2015 Jan 1.
9
Seven novel coordination polymers constructed by rigid 4-(4-carboxyphenyl)-terpyridine ligands: synthesis, structural diversity, luminescence and magnetic properties.七种由刚性 4-(4-羧基苯基)-2,2’:6’,2”-三联吡啶配体构筑的新型配位聚合物的合成、结构多样性、发光和磁性。
Dalton Trans. 2014 Jan 21;43(3):1460-70. doi: 10.1039/c3dt52500g. Epub 2013 Nov 8.
10
New software for searching the Cambridge Structural Database and visualizing crystal structures.用于搜索剑桥结构数据库和可视化晶体结构的新软件。
Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):389-97. doi: 10.1107/s0108768102003324. Epub 2002 May 29.