• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

配位组装中的竞争：基于Co(NCS)和4'-(4-甲氧基苯基)-3,2':6',3″-三联吡啶的一维配位聚合物或二维网络

Competition in Coordination Assemblies: 1D-Coordination Polymer or 2D-Nets Based on Co(NCS) and 4'-(4-methoxyphenyl)-3,2':6',3″-terpyridine.

作者信息

Rocco Dalila, Prescimone Alessandro, Klein Y Maximilian, Gawryluk Dariusz J, Constable Edwin C, Housecroft Catherine E

机构信息

Department of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, Switzerland.

Laboratory for Multiscale Materials Experiments, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland.

出版信息

Polymers (Basel). 2019 Jul 23;11(7):1224. doi: 10.3390/polym11071224.

DOI:10.3390/polym11071224
PMID:31340430
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6680941/
Abstract

The synthesis and characterization of 4'-(4-methoxyphenyl)-3,2':6',3″-terpyridine () (IUPAC PIN 2-(4-methoxyphenyl)-1,2:2,3-terpyridine) are described, and its coordination behaviour with cobalt(II) thiocyanate has been investigated. In a series of experiments, crystals were grown at room temperature by layering a MeOH solution of Co(NCS) over a CHCl solution of using 1:1, 1:2 or 2:1 molar ratios of metal salt-to-ligand. Crystals harvested within 2-3 weeks proved to be the 1D-coordination polymer [Co()(NCS)(MeOH)] and powder X-ray diffraction (PXRD) confirmed that the crystals selected for single-crystal X-ray diffraction were representative of the bulk samples. Longer crystallization times with a Co(NCS) to molar ratio of 1:1 yielded crystals of [Co()(NCS)(MeOH)] (1D-chain) and the pseudopolymorphs [{Co()(NCS)}·3MeOH] and [{Co()(NCS)}·2.2CHCl] ((4,4)-nets), each type of crystal originating from a different zone in the crystallization tube. PXRD for this last experiment confirmed that the dominant product in the bulk sample was the 1D-coordination polymer.

摘要

描述了4'-(4-甲氧基苯基)-3,2':6',3″-三联吡啶（IUPAC PIN 2-(4-甲氧基苯基)-1,2:2,3-三联吡啶）的合成与表征，并研究了其与硫氰酸钴(II)的配位行为。在一系列实验中，通过将Co(NCS)的甲醇溶液以金属盐与配体1:1、1:2或2:1的摩尔比覆盖在的CHCl溶液上，在室温下生长晶体。在2-3周内收获的晶体被证明是一维配位聚合物[Co()(NCS)(MeOH)]，粉末X射线衍射（PXRD）证实，为单晶X射线衍射选择的晶体代表了块状样品。Co(NCS)与的摩尔比为1:1时更长的结晶时间产生了[Co()(NCS)(MeOH)]（一维链）晶体以及假多晶型物[{Co()(NCS)}·3MeOH]和[{Co()(NCS)}·2.2CHCl]（(4,4)-网络），每种晶体都来自结晶管中的不同区域。最后一个实验的PXRD证实，块状样品中的主要产物是一维配位聚合物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/5446b18de654/polymers-11-01224-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/49896405e4a4/polymers-11-01224-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/56361edf2fbf/polymers-11-01224-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/a32ea1e933d9/polymers-11-01224-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/7ffeed5d388f/polymers-11-01224-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/aadd1d83e28a/polymers-11-01224-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/30f75ccf8cc9/polymers-11-01224-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/2ae5597fd960/polymers-11-01224-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/439f1ae4e3ae/polymers-11-01224-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/7253045422be/polymers-11-01224-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/eba7b7a27e02/polymers-11-01224-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/dfe90e8ec91b/polymers-11-01224-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/e31cd799f79b/polymers-11-01224-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/5446b18de654/polymers-11-01224-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/49896405e4a4/polymers-11-01224-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/56361edf2fbf/polymers-11-01224-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/a32ea1e933d9/polymers-11-01224-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/7ffeed5d388f/polymers-11-01224-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/aadd1d83e28a/polymers-11-01224-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/30f75ccf8cc9/polymers-11-01224-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/2ae5597fd960/polymers-11-01224-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/439f1ae4e3ae/polymers-11-01224-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/7253045422be/polymers-11-01224-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/eba7b7a27e02/polymers-11-01224-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/dfe90e8ec91b/polymers-11-01224-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/e31cd799f79b/polymers-11-01224-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5047/6680941/5446b18de654/polymers-11-01224-g010.jpg

相似文献

1
Competition in Coordination Assemblies: 1D-Coordination Polymer or 2D-Nets Based on Co(NCS) and 4'-(4-methoxyphenyl)-3,2':6',3″-terpyridine.配位组装中的竞争：基于Co(NCS)和4'-(4-甲氧基苯基)-3,2':6',3″-三联吡啶的一维配位聚合物或二维网络
Polymers (Basel). 2019 Jul 23;11(7):1224. doi: 10.3390/polym11071224.
2
Directing 2D-Coordination Networks: Combined Effects of a Conformationally Flexible 3,2':6',3″-Terpyridine and Chain Length Variation in 4'-(4--Alkyloxyphenyl) Substituents.指导二维配位网络：构象柔性 3,2':6',3″-三联吡啶与 4'-(4--烷氧基苯基)取代基链长变化的综合影响。
Molecules. 2020 Apr 4;25(7):1663. doi: 10.3390/molecules25071663.
3
Straight Versus Branched Chain Substituents in 4'-(Butoxyphenyl)-3,2':6',3″-terpyridines: Effects on (4,4) Coordination Network Assemblies.4'-(丁氧基苯基)-3,2':6',3″-三联吡啶中的直链与支链取代基：对(4,4)配位网络组装体的影响
Polymers (Basel). 2020 Aug 14;12(8):1823. doi: 10.3390/polym12081823.
4
4,2':6',4"- and 3,2':6',3"-Terpyridines: The Conflict between Well-Defined Vectorial Properties and Serendipity in the Assembly of 1D-, 2D- and 3D-Architectures.4,2':6',4"-和3,2':6',3"-三联吡啶：一维、二维和三维结构组装中明确的矢量性质与意外发现之间的冲突
Materials (Basel). 2017 Jun 30;10(7):728. doi: 10.3390/ma10070728.
5
A Tail Does Not Always Make a Difference: Assembly of Nets from Co(NCS) and 1,4-bis(-Alkyloxy)-2,5-bis(3,2':6',3″-terpyridin-4'-yl)benzene Ligands.尾巴并非总是关键所在：由Co(NCS)与1,4-双（-烷氧基）-2,5-双（3,2':6',3″-三联吡啶-4'-基）苯配体组装而成的网状结构
Molecules. 2022 Aug 5;27(15):4995. doi: 10.3390/molecules27154995.
6
Correction: Rocco, D.; et al. Competition in Coordination Assemblies: 1D-Coordination Polymer or 2D-Nets Based on Co(NCS) and 4'-(4-methoxy)-3,2':6',3″-terpyridine. 2019, , 1224; doi:10.3390/polym11071224.更正：罗科，D.；等人。配位组装中的竞争：基于Co(NCS)和4'-(4-甲氧基)-3,2':6',3″-三联吡啶的一维配位聚合物或二维网络。2019年，，1224；doi:10.3390/polym11071224 。
Polymers (Basel). 2019 Sep 20;11(10):1537. doi: 10.3390/polym11101537.
7
Four Novel Zn (II) Coordination Polymers Based on 4'-Ferrocenyl-3,2':6',3''-Terpyridine: Engineering a Switch from 1D Helical Polymer Chain to 2D Network by Coordination Anion Modulation.基于4'-二茂铁基-3,2':6',3''-三联吡啶的四种新型锌（II）配位聚合物：通过配位阴离子调控实现从一维螺旋聚合物链到二维网络的转变
Materials (Basel). 2017 Nov 27;10(12):1360. doi: 10.3390/ma10121360.
8
Adapting (4,4) Networks through Substituent Effects and Conformationally Flexible 3,2':6',3"-Terpyridines.通过取代效应和构象柔性 3,2':6',3"-三联吡啶来适应（4,4）网络。
Molecules. 2021 Oct 20;26(21):6337. doi: 10.3390/molecules26216337.
9
Sometimes the Same, Sometimes Different: Understanding Self-Assembly Algorithms in Coordination Networks.有时相同，有时不同：理解配位网络中的自组装算法
Polymers (Basel). 2018 Dec 11;10(12):1369. doi: 10.3390/polym10121369.
10
The synthesis and characterisation of coordination and hydrogen-bonded networks based on 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoic acid.基于4-(3,5-二甲基-1H-吡唑-4-基)苯甲酸的配位和氢键网络的合成与表征
Dalton Trans. 2015 May 21;44(19):9269-80. doi: 10.1039/c5dt00011d.

引用本文的文献

1
Straight Versus Branched Chain Substituents in 4'-(Butoxyphenyl)-3,2':6',3″-terpyridines: Effects on (4,4) Coordination Network Assemblies.4'-(丁氧基苯基)-3,2':6',3″-三联吡啶中的直链与支链取代基：对(4,4)配位网络组装体的影响
Polymers (Basel). 2020 Aug 14;12(8):1823. doi: 10.3390/polym12081823.
2
Directing 2D-Coordination Networks: Combined Effects of a Conformationally Flexible 3,2':6',3″-Terpyridine and Chain Length Variation in 4'-(4--Alkyloxyphenyl) Substituents.指导二维配位网络：构象柔性 3,2':6',3″-三联吡啶与 4'-(4--烷氧基苯基)取代基链长变化的综合影响。
Molecules. 2020 Apr 4;25(7):1663. doi: 10.3390/molecules25071663.
3

本文引用的文献

1
Ditopic and Tetratopic 4,2':6',4''-Terpyridines as Structural Motifs in 2D- and 3D-Coordination Assemblies.双齿和四齿4,2':6',4''-三联吡啶作为二维和三维配位组装体中的结构基序
Chimia (Aarau). 2019 Jul 26;73(6):462-467. doi: 10.2533/chimia.2019.462.
2
Synthesis of Terpyridines: Simple Reactions-What Could Possibly Go Wrong?嘧啶类化合物的合成：简单反应——可能会出什么问题？
Molecules. 2019 May 9;24(9):1799. doi: 10.3390/molecules24091799.
3
Sometimes the Same, Sometimes Different: Understanding Self-Assembly Algorithms in Coordination Networks.
Single and Double-Stranded 1D-Coordination Polymers with 4'-(4-Alkyloxyphenyl)-3,2':6',3"-terpyridines and {Cu(μ-OAc)} or {Cu(μ-OH)(μ-OAc)(μ-OAc)(AcO-κ)} Motifs.
含4'-(4-烷氧基苯基)-3,2':6',3"-三联吡啶以及{Cu(μ-OAc)}或{Cu(μ-OH)(μ-OAc)(μ-OAc)(AcO-κ)}基序的单链和双链一维配位聚合物
Polymers (Basel). 2020 Feb 4;12(2):318. doi: 10.3390/polym12020318.
4
Correction: Rocco, D.; et al. Competition in Coordination Assemblies: 1D-Coordination Polymer or 2D-Nets Based on Co(NCS) and 4'-(4-methoxy)-3,2':6',3″-terpyridine. 2019, , 1224; doi:10.3390/polym11071224.更正：罗科，D.；等人。配位组装中的竞争：基于Co(NCS)和4'-(4-甲氧基)-3,2':6',3″-三联吡啶的一维配位聚合物或二维网络。2019年，，1224；doi:10.3390/polym11071224 。
Polymers (Basel). 2019 Sep 20;11(10):1537. doi: 10.3390/polym11101537.
有时相同，有时不同：理解配位网络中的自组装算法
Polymers (Basel). 2018 Dec 11;10(12):1369. doi: 10.3390/polym10121369.
4
Crystal Engineering: An Outlook for the Future.晶体工程：未来展望
Angew Chem Int Ed Engl. 2019 Mar 22;58(13):4100-4107. doi: 10.1002/anie.201811313. Epub 2019 Feb 27.
5
Metal-Organic Frameworks for Separation.金属有机骨架材料用于分离。
Adv Mater. 2018 Sep;30(37):e1705189. doi: 10.1002/adma.201705189. Epub 2018 Mar 27.
6
Progress and prospect of adsorptive removal of heavy metal ions from aqueous solution using metal-organic frameworks: A review of studies from the last decade.金属有机骨架材料用于水溶液中重金属离子吸附去除的研究进展及展望：对过去十年研究的综述。
Chemosphere. 2018 Jun;201:627-643. doi: 10.1016/j.chemosphere.2018.03.047. Epub 2018 Mar 6.
7
Synthesis, functionalization, and applications of metal-organic frameworks in biomedicine.金属有机骨架在生物医学中的合成、功能化及应用。
Dalton Trans. 2018 Feb 13;47(7):2114-2133. doi: 10.1039/c7dt04116k.
8
Tuning Proton Conductivity by Interstitial Guest Change in Size-Adjustable Nanopores of a Cu -MOF: A Potential Platform for Versatile Proton Carriers.通过铜-金属有机框架尺寸可调纳米孔中间隙客体变化调节质子传导率：多功能质子载体的潜在平台
Chemistry. 2016 Nov 2;22(45):16277-16285. doi: 10.1002/chem.201601964. Epub 2016 Sep 23.
9
The Cambridge Structural Database.剑桥结构数据库。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Apr;72(Pt 2):171-9. doi: 10.1107/S2052520616003954. Epub 2016 Apr 1.
10
From self-sorted coordination libraries to networking nanoswitches for catalysis.从自分类配位库到用于催化的网络化纳米开关
Chem Commun (Camb). 2015 Oct 18;51(81):14956-68. doi: 10.1039/c5cc06605k.