Louisy Elodie, Khodyrieva Veronika, Olivero Sandra, Michelet Véronique, Mija Alice
Institut de Chimie de Nice, University Côte d'Azur, 28 Avenue Valrose, 06108, Nice cedex 2, France.
Chempluschem. 2022 Aug;87(8):e202200190. doi: 10.1002/cplu.202200190.
(R)-Limonene, a renewable terpene, and its epoxidized derivatives, i. e. limonene epoxides, have prompted growing attention over the last decade as building blocks for the synthesis of biobased monomers and polymers. With the goal of replacing petroleum-based polymers several polymerization techniques have been applied on limonene oxide and limonene dioxide monomers. This paper aims to contribute to the literature by presenting a review dedicated to limonene oxide and dioxide as raw monomers of renewable origin for the development of biobased polymers. The polymerization techniques described are namely the homopolymerization, the copolymerization with carbon dioxide and anhydrides, and the copolymerization of limonene epoxide-based monomers. Limonene oxide polymerizations will be investigated first, followed by limonene dioxide polymerizations.
（R）-柠檬烯是一种可再生萜烯，及其环氧化衍生物，即氧化柠檬烯，在过去十年中作为合成生物基单体和聚合物的基础原料受到越来越多的关注。为了取代石油基聚合物，人们对氧化柠檬烯和二氧化柠檬烯单体应用了多种聚合技术。本文旨在通过对氧化柠檬烯和二氧化柠檬烯作为可再生来源的生物基聚合物开发的原始单体进行综述，为相关文献做出贡献。所描述的聚合技术包括均聚、与二氧化碳和酸酐的共聚，以及基于氧化柠檬烯单体的共聚。首先将研究氧化柠檬烯的聚合，然后是二氧化柠檬烯的聚合。
