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纤维素:可充电电池的特性与应用

Cellulose: Characteristics and applications for rechargeable batteries.

作者信息

Muddasar Muhammad, Beaucamp A, Culebras Mario, Collins Maurice N

机构信息

Stokes Laboratories, School of Engineering, Bernal Institute, University of Limerick, Limerick, Ireland; Advanced Materials and Bioengineering Research (AMBER) Centre, Ireland.

Stokes Laboratories, School of Engineering, Bernal Institute, University of Limerick, Limerick, Ireland.

出版信息

Int J Biol Macromol. 2022 Oct 31;219:788-803. doi: 10.1016/j.ijbiomac.2022.08.026. Epub 2022 Aug 10.

DOI:10.1016/j.ijbiomac.2022.08.026
PMID:35963345
Abstract

Cellulose, an abundant natural polymer, has promising potential to be used for energy storage systems because of its excellent mechanical, structural, and physical characteristics. This review discusses the structural features of cellulose and describes its potential application as an electrode, separator, and binder, in various types of high-performing batteries. Various surface and structural characteristics of cellulose (e.g., fiber size, surface functional groups, the hierarchy of pores, and porosity levels) that contribute to its electrochemical performance are discussed. Cellulose structure/property/processing/function relationships are further focused and elucidated in terms of the latest developments in the emerging field of sustainable materials in Li-Ion, Na-Ion, and LiS batteries.

摘要

纤维素是一种丰富的天然聚合物,因其优异的机械、结构和物理特性,在储能系统中具有广阔的应用潜力。本文综述了纤维素的结构特征,并描述了其在各类高性能电池中作为电极、隔膜和粘结剂的潜在应用。文中讨论了有助于纤维素电化学性能的各种表面和结构特征(如纤维尺寸、表面官能团、孔隙层级和孔隙率水平)。基于锂离子电池、钠离子电池和锂硫电池等可持续材料新兴领域的最新进展,进一步聚焦并阐明了纤维素的结构/性能/加工/功能关系。

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