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基于芦荟大黄素改性的抗菌及碱响应性阳离子水性聚氨酯

Antibacterial and Alkali-responsive Cationic Waterborne Polyurethane Based on Modification of Aloe Emodin.

作者信息

Xiong Xiaoyan, Li Xiaobin, Zhu Zifan, Zhang Ending, Shi Jun, Lu Mangeng

机构信息

Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou, 510650 P. R. China.

University of Chinese Academy of Sciences, Beijing, 100049 China.

出版信息

Chem Res Chin Univ. 2023;39(2):266-275. doi: 10.1007/s40242-022-2179-6. Epub 2022 Aug 4.

Abstract

Cationic water-based polyurethane(CWPU) was synthesized to explore aloe-emodin modifies to obtain CWPU materials with better comprehensive performance. It provides a simple way to synthesize antibacterial waterborne polyurethane, which is to introduce the end-blocking group of herbal extracts into the structure. It contains synergistic antibacterial effect of herbal antibacterial and quaternary ammonium ion on . It makes the material resist the erosion of bacterial, and increase the service life of materials. When the pH value of the environment changes, the UV absorbance of the aloe-emodin modified cationic water-based polyurethane(AE-CWPU) also changes. Therefore, within a certain detection range, AE-CWPU has great applications in the field of smart response materials. The modified thermodynamic properties have been improved, and the mechanical properties basically maintained the maximum stress, and the elongation at break was reduced.

摘要

合成了阳离子水性聚氨酯(CWPU),以探索大黄素改性以获得具有更好综合性能的CWPU材料。它提供了一种合成抗菌水性聚氨酯的简单方法,即将草药提取物的封端基团引入结构中。它含有草药抗菌和季铵离子的协同抗菌作用。它使材料抵抗细菌的侵蚀,并延长材料的使用寿命。当环境的pH值变化时,大黄素改性阳离子水性聚氨酯(AE-CWPU)的紫外吸光度也会发生变化。因此,在一定的检测范围内,AE-CWPU在智能响应材料领域有很大的应用。改性后的热力学性能得到了改善,力学性能基本保持了最大应力,断裂伸长率降低。

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