Hu Xiao-Hua, Zhang Rui, Wu Zhiyong, Xiong Shisheng
School of Information Science and Technology, Fudan University, 220 Handan Road, Shanghai 200433, China.
ACS Omega. 2022 Jul 31;7(31):27263-27271. doi: 10.1021/acsomega.2c02159. eCollection 2022 Aug 9.
Graphene is one of the most promising nanomaterials with many extraordinary properties and numerous exciting applications. In this work, a green, facile, and rapid method was developed to prepare graphene directly from common biomass materials such as banana peels, cantaloupe peels, coconut peels, and orange peels by using concentrated solar radiation. The basic principle of this method is photothermal conversion. On a sunny day, the sunlight was concentrated by a biconvex lens to form a focused light spot with a high temperature above 1000 °C, which can directly convert fruit peels into graphene nanosheets within 2-3 s. The product is named concentrated-solar-induced graphene (CSIG) based on the process employed to generate it. The resulting CSIG was characterized using a range of analytical techniques. The Raman spectrum of the CSIG displayed two distinct peaks corresponding to the D and G bands at ∼1343 and ∼1568 cm, respectively. Scanning electron microscopy, transmission electron microscopy, and X-ray diffraction were used to confirm that the CSIG consists of a few layers of turbostratic graphene nanosheets. Atomic force microscopy characterization revealed that the CSIG nanosheets have a thickness of ∼4 nm. The antibacterial potential of the CSIG was also explored. The CSIG had a strong inhibitory effect on the growth of . This simple, green, and straightforward method for producing graphene may open a new route for turning waste into useful materials: an inexhaustible and pollution-free natural resource can be readily exploited by using a solar tracker-lens system for the large-scale production of graphene materials directly from low-cost biomass materials.
石墨烯是最具前景的纳米材料之一,具有许多非凡特性和众多令人兴奋的应用。在这项工作中,开发了一种绿色、简便且快速的方法,通过利用聚光太阳能辐射,直接从香蕉皮、哈密瓜皮、椰子皮和橙子皮等常见生物质材料制备石墨烯。该方法的基本原理是光热转换。在晴天,阳光通过双凸透镜聚焦形成温度高于1000℃的聚焦光斑,可在2 - 3秒内将果皮直接转化为石墨烯纳米片。基于其生成过程,该产物被命名为聚光太阳能诱导石墨烯(CSIG)。使用一系列分析技术对所得的CSIG进行了表征。CSIG的拉曼光谱分别在约1343和约1568cm处显示出对应于D带和G带的两个明显峰。扫描电子显微镜、透射电子显微镜和X射线衍射用于确认CSIG由几层乱层石墨烯纳米片组成。原子力显微镜表征显示CSIG纳米片的厚度约为4nm。还探索了CSIG的抗菌潜力。CSIG对……的生长具有强烈抑制作用。这种简单、绿色且直接的石墨烯生产方法可能为将废物转化为有用材料开辟一条新途径:通过使用太阳能跟踪器 - 透镜系统,可以轻松利用一种取之不尽且无污染的自然资源,直接从低成本生物质材料大规模生产石墨烯材料。