Assessment of biotoxicity of three types of landfilled foundry waste on the basis of dehydrogenase activity.

The microbiological activity of three types of landfilled foundry wastes, i.e. biologically reclaimed foundry waste (BFW), foundry waste landfilled since the 1990s (LFW) and fresh foundry waste (FFW), was investigated. The wastes originated from a Polish iron and steel foundry which uses organic binders based on phenol-formaldehyde resins and mineral binders to casting production. The physical and chemical properties and dehydrogenase activity (DHA) were determined in the waste samples and local soils. In addition, a pot experiment was performed to determine the effect of the addition of FFW with no microbial activity on soils. Additional correlation analysis was conducted between DHA and other parameters. It was found that biologically reclaimed foundry waste (BFW) showed the highest microbial activity, similar to soils from garden allotments and agricultural fields. The DHA in LFW was about a half lower than BFW. On the other hand, FFW did not show any microbial activity. A pot experiment showed that increasing the percentage of foundry waste relative to soil had a negative effect on DHA, probably as a result of soil dilution rather than the inhibitory effect of contaminants. It was concluded that the optimum addition of FFW to soils is 10% wt, due to the highest value of DHA among the other variants.