State Key Laboratory for Reliability and Intelligence of Electrical Equipment, Hebei Key Laboratory of Smart Sensing and Human-Robot Interaction, School of Mechanical Engineering, Hebei University of Technology, Tianjin, 300401, China.
State Key Laboratory of Reliability and Intelligence of Electrical Equipment, School of Health Sciences and Biomedical Engineering, Hebei University of Technology, Tianjin 300130, China.
Nanoscale. 2022 Sep 2;14(34):12418-12430. doi: 10.1039/d2nr03277e.
Functional fibers have attracted much research attention due to their potential application in developing advanced electronic textiles for wearable devices. However, challenges still exist in preparing high-performance fiber-shaped sensors with superior flexibility and stretchability while achieving a high sensitivity and a wide detection range. Herein, we propose the design and fabrication of an ultra-flexible and super-elastic fiber-shaped strain sensor a facile combining approach of wet-spinning and dip-coating. The sensor adopts a core-sheath configuration of liquid metal droplets dispersed in porous thermoplastic polyurethane as a substrate core and a carbon nanotube intertwined network embedding silver nanowires as a strain sensitive sheath. By taking advantage of both the composition of multiple functional materials and the design of a microstructured device configuration, the developed fiber-shaped sensor exhibits an ultrahigh sensitivity (maximum gauge factor of 7336.1), an extremely large workable strain range (500%), a low strain detection limit (0.5%), a fast response time (200 ms) and good stability (10 000 cycles). In addition, the sensor is temperature insensitive, inert under harsh solution conditions, degradable and recyclable. Intriguingly, the fiber-shaped sensor can be used to detect various human motions and gestures by directly attaching to skins or elaborately weaving into textiles, demonstrating its great potential in human healthcare monitoring and human-machine interactions.
功能纤维由于在开发用于可穿戴设备的先进电子纺织品方面具有潜在应用而引起了广泛的研究关注。然而,在制备具有优异的灵活性和可拉伸性的高性能纤维状传感器的同时,仍然存在挑战,以实现高灵敏度和宽检测范围。在此,我们提出了一种超柔软和超弹性纤维状应变传感器的设计和制造,这是一种通过湿法纺丝和浸涂相结合的简便方法。该传感器采用了液态金属液滴分散在多孔热塑性聚氨酯中的核壳结构作为基底核心,以及嵌入银纳米线的碳纳米管交织网络作为应变敏感壳。通过利用多种功能材料的组成和微结构器件配置的设计,所开发的纤维状传感器表现出超高的灵敏度(最大应变系数为 7336.1)、极大的工作应变范围(500%)、低应变检测下限(0.5%)、快速响应时间(200ms)和良好的稳定性(10000 次循环)。此外,该传感器对温度不敏感,在恶劣溶液条件下呈惰性,可降解且可回收。有趣的是,该纤维状传感器可通过直接附着在皮肤或精心编织成纺织品上,用于检测各种人体运动和手势,这表明其在人体健康监测和人机交互方面具有巨大的应用潜力。