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高拉伸性核壳纤维的湿法纺丝及其在可穿戴应变传感器中的应用。

Highly Stretchable Core-Sheath Fibers via Wet-Spinning for Wearable Strain Sensors.

机构信息

School of Mechanical Engineering, Xi'an Jiaotong University , Xi'an 710049, P. R. China.

出版信息

ACS Appl Mater Interfaces. 2018 Feb 21;10(7):6624-6635. doi: 10.1021/acsami.7b18677. Epub 2018 Feb 12.

DOI:10.1021/acsami.7b18677
PMID:29384359
Abstract

Lightweight, stretchable, and wearable strain sensors have recently been widely studied for the development of health monitoring systems, human-machine interfaces, and wearable devices. Herein, highly stretchable polymer elastomer-wrapped carbon nanocomposite piezoresistive core-sheath fibers are successfully prepared using a facile and scalable one-step coaxial wet-spinning assembly approach. The carbon nanotube-polymeric composite core of the stretchable fiber is surrounded by an insulating sheath, similar to conventional cables, and shows excellent electrical conductivity with a low percolation threshold (0.74 vol %). The core-sheath elastic fibers are used as wearable strain sensors, exhibiting ultra-high stretchability (above 300%), excellent stability (>10 000 cycles), fast response, low hysteresis, and good washability. Furthermore, the piezoresistive core-sheath fiber possesses bending-insensitiveness and negligible torsion-sensitive properties, and the strain sensing performance of piezoresistive fibers maintains a high degree of stability under harsh conditions. On the basis of this high level of performance, the fiber-shaped strain sensor can accurately detect both subtle and large-scale human movements by embedding it in gloves and garments or by directly attaching it to the skin. The current results indicate that the proposed stretchable strain sensor has many potential applications in health monitoring, human-machine interfaces, soft robotics, and wearable electronics.

摘要

近年来,用于开发健康监测系统、人机界面和可穿戴设备的轻质、可拉伸和可穿戴应变传感器受到了广泛的研究。在此,通过一种简单且可扩展的一步同轴湿法纺丝组装方法,成功制备了具有高拉伸性的聚合物弹性体包裹碳纳米复合材料压阻芯鞘纤维。可拉伸纤维的碳纳米管-聚合物复合芯被类似于传统电缆的绝缘鞘包围,表现出优异的导电性,具有低渗滤阈值(0.74 体积%)。这种弹性纤维可作为可穿戴应变传感器,具有超高的拉伸性(超过 300%)、出色的稳定性(超过 10000 次循环)、快速响应、低滞后和良好的可洗性。此外,压阻芯鞘纤维具有弯曲不敏感和几乎没有扭转敏感的特性,在恶劣条件下,压阻纤维的应变传感性能仍保持高度稳定。基于这种高性能,纤维状应变传感器通过嵌入手套和服装或直接贴附在皮肤上,能够精确地检测细微和大幅度的人体运动。目前的结果表明,所提出的可拉伸应变传感器在健康监测、人机界面、软机器人和可穿戴电子领域具有许多潜在的应用。

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