• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

水合μ-氧杂-双-{双-[3-甲基-5-(吡啶-2-基)-1,2,4-三唑]铁(II)}双-(甲苯磺酸盐)2.75水合物的合成与晶体结构

Synthesis and crystal structure of hydrated μ-oxa-lato-bis-{bis-[3-methyl-5-(pyridin-2-yl)-1-1,2,4-triazole]iron(II)} bis-(toluene-sulfonate) 2.75-hydrate.

作者信息

Petrenko Yuliia P, Bibik Yurii S, Khomenko Dmytro M, Doroshchuk Roman O, Gural'skiy Il'ya A, Shova Sergiu, Lampeka Rostyslav D, Raspertova Ilona V

机构信息

Department of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska, st. 64, Kyiv, Ukraine.

Enamine Ltd., Chervonotkatska Street 78, Kyiv 02094, Ukraine.

出版信息

Acta Crystallogr E Crystallogr Commun. 2022 Jul 26;78(Pt 8):829-832. doi: 10.1107/S2056989022007460. eCollection 2022 Aug 1.

DOI:10.1107/S2056989022007460
PMID:35974812
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9361385/
Abstract

In the title compound Fe(CO)(CHN)·2.75HO, the two Fe ions have a highly distorted octa-hedral FeNO environment formed by two bidentate triazole-based chelating ligands and a bis-bidentate oxalate bridging anion that connects the metal ions. Stabilization within the crystal structure is provided a system of O-H⋯O and N-H⋯O hydrogen bonding, which determines the formation of a two-dimensional architecture along the axis direction.

摘要

在标题化合物Fe(CO)(CHN)·2.75HO中，两个铁离子具有高度扭曲的八面体FeNO环境，该环境由两个双齿三唑基螯合配体和一个连接金属离子的双齿草酸根桥连阴离子形成。晶体结构中的稳定性由O-H⋯O和N-H⋯O氢键体系提供，这决定了沿轴方向形成二维结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e51/9361385/e272b49758c5/e-78-00829-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e51/9361385/72fa0ee8ee3a/e-78-00829-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e51/9361385/43ada2d6c176/e-78-00829-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e51/9361385/e272b49758c5/e-78-00829-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e51/9361385/72fa0ee8ee3a/e-78-00829-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e51/9361385/43ada2d6c176/e-78-00829-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e51/9361385/e272b49758c5/e-78-00829-fig3.jpg

相似文献

1
Synthesis and crystal structure of hydrated μ-oxa-lato-bis-{bis-[3-methyl-5-(pyridin-2-yl)-1-1,2,4-triazole]iron(II)} bis-(toluene-sulfonate) 2.75-hydrate.水合μ-氧杂-双-{双-[3-甲基-5-(吡啶-2-基)-1,2,4-三唑]铁(II)}双-(甲苯磺酸盐)2.75水合物的合成与晶体结构
Acta Crystallogr E Crystallogr Commun. 2022 Jul 26;78(Pt 8):829-832. doi: 10.1107/S2056989022007460. eCollection 2022 Aug 1.
2
Crystal structure of -poly[[[tetra-aqua-iron(II)]--μ-1,2-bis-(pyridin-4-yl)ethene-κ:'] bis-(-toluene-sulfonate) methanol disolvate].-聚[[[四水合铁（II）] - μ - 1,2 - 双 - （吡啶 - 4 - 基）乙烯 - κ:']双 - （对甲苯磺酸盐）甲醇溶剂合物]的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Nov 30;73(Pt 12):1977-1980. doi: 10.1107/S2056989017017054. eCollection 2017 Dec 1.
3
Crystal structures of two Cu compounds: -poly[[chlorido-copper(II)]-μ--[eth-oxy(pyridin-2-yl)methyl-idene]-'-[oxido(pyridin-3-yl)methyl-idene]hydrazine-κ ,',:''] and di-μ-chlorido-1:4κ :-2:3κ :-di-chlorido-2κ,4κ-bis[μ-eth-oxy(pyridin-2-yl)methano-lato-1:2:3κ :,:;1:3:4κ ::,]bis-[μ-eth-oxy(pyridin-2-yl)methano-lato-1:2κ ,:;3:4κ ,:]tetracopper(II).两种铜化合物的晶体结构：-聚[[氯合铜（II）]-μ--[乙氧基（吡啶-2-基）亚甲基]-'-[氧化（吡啶-3-基）亚甲基]肼-κ，',:']和二-μ-氯代-1:4κ :-2:3κ :-二氯代-2κ,4κ-双[μ-乙氧基（吡啶-2-基）甲醇酸根-1:2:3κ :,:;1:3:4κ ::,]双-[μ-乙氧基（吡啶-2-基）甲醇酸根-1:2κ ,:;3:4κ ,:]四铜（II） 。
Acta Crystallogr E Crystallogr Commun. 2019 Jun 28;75(Pt 7):1069-1075. doi: 10.1107/S2056989019008922. eCollection 2019 Jul 1.
4
Crystal structure of poly[{μ-N,N'-bis[(pyridin-4-yl)meth-yl]oxalamide}-μ-oxalato-cobalt(II)].聚[{μ-N,N'-双[(吡啶-4-基)甲基]草酰胺}-μ-草酸根合钴(II)]的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Aug 1;70(Pt 9):m307-8. doi: 10.1107/S1600536814015608. eCollection 2014 Sep 1.
5
Crystal structures of {[Cu(Lpn)2][Fe(CN)5(NO)]·H2O} n and {[Cu(Lpn)2]3[Cr(CN)6]2·5H2O} n [where Lpn = (R)-propane-1,2-di-amine]: two heterometallic chiral cyanide-bridged coordination polymers.{[Cu(Lpn)₂][Fe(CN)₅(NO)]·H₂O}ₙ 和 {[Cu(Lpn)₂]₃[Cr(CN)₆]₂·5H₂O}ₙ 的晶体结构 [其中 Lpn = (R)-丙烷-1,2-二胺]：两种异金属手性氰基桥联配位聚合物。
Acta Crystallogr E Crystallogr Commun. 2015 Mar 21;71(Pt 4):392-7. doi: 10.1107/S2056989015005253. eCollection 2015 Apr 1.
6
μ-Oxalato-κO,O:O,O-bis-[diaqua-(2,2'-bipyridyl-κN,N')zinc] bis-[2-(1H-benzotriazol-1-yl)acetate] hexa-hydrate.μ-草酸根-κO,O:O,O-双-[二水合-(2,2'-联吡啶-κN,N')锌] 双-[2-(1H-苯并三唑-1-基)乙酸] 六水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m196. doi: 10.1107/S1600536812001778. Epub 2012 Jan 21.
7
Crystal structures of μ-oxalato-bis-[azido-(hista-mine)-copper(II)] and μ-oxalato-bis-[(dicyan-amido)(hista-mine)-copper(II)].μ-草酸根双[叠氮基-（组胺）-铜（II）]和μ-草酸根双[（二氰胺基）（组胺）-铜（II）]的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Oct 28;71(Pt 11):1379-83. doi: 10.1107/S2056989015019908. eCollection 2015 Nov 1.
8
Synthesis and crystal structure of a new copper(II) complex based on 5-ethyl-3-(pyridin-2-yl)-1,2,4-triazole.基于5-乙基-3-(吡啶-2-基)-1,2,4-三唑的新型铜(II)配合物的合成与晶体结构
Acta Crystallogr E Crystallogr Commun. 2023 Apr 14;79(Pt 5):432-435. doi: 10.1107/S2056989023003079. eCollection 2023 Apr 1.
9
Crystal structure of 4-(di-methyl-amino)-pyridinium cis-di-aqua-bis-(oxalato-κ(2) O,O')ferrate(III) hemihydrate.4-（二甲基氨基）吡啶鎓顺式-二水合-双（草酸根-κ（2）O，O'）铁（III）半水合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jul 15;71(Pt 8):934-6. doi: 10.1107/S2056989015013213. eCollection 2015 Aug 1.
10
Diaqua-bis-{4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonato-κ(2)N,N'}nickel(II) tetra-hydrate.二水合双-{4-[(吡啶-2-基)亚甲基氨基]苯磺酸根-κ(2)N,N'}镍(II)四水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m809-10. doi: 10.1107/S1600536812022179. Epub 2012 May 26.

引用本文的文献

1
Stepwise Spin Transitions of Spin-Crossover Complexes Based in 3-(2-Pyridyl)-1,2,4-triazole Ligands Associated with Symmetry Change in Hydrogen Bonding Interactions.基于3-(2-吡啶基)-1,2,4-三唑配体的自旋交叉配合物的逐步自旋转变与氢键相互作用中的对称性变化相关。
Inorg Chem. 2025 Apr 7;64(13):6442-6451. doi: 10.1021/acs.inorgchem.4c04952. Epub 2025 Mar 25.

本文引用的文献

1
An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties.以三唑衍生物为配体的两种铜（II）配合物的研究：磁性和催化性质
RSC Adv. 2021 Jul 2;11(38):23442-23449. doi: 10.1039/d1ra03107d. eCollection 2021 Jul 1.
2
Structural and magnetic characterization of Ni(ii), Co(ii), and Fe(ii) binuclear complexes on a bis(pyridyl-triazolyl)alkane basis.基于双（吡啶基 - 三唑基）烷烃的镍（II）、钴（II）和铁（II）双核配合物的结构与磁性表征
Dalton Trans. 2019 Jul 16;48(28):10526-10536. doi: 10.1039/c9dt01391a.
3
The Cambridge Structural Database.
剑桥结构数据库。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Apr;72(Pt 2):171-9. doi: 10.1107/S2052520616003954. Epub 2016 Apr 1.
4
An intuitional hierarchical assembly of cluster-organic frameworks with a thickness of 1.97 nm from a discrete Co14 cluster.
Chem Commun (Camb). 2015 May 4;51(36):7598-601. doi: 10.1039/c5cc01057h.
5
Switching a 2D Co(II) layer to a 3D Co7-cluster-based metal-organic framework: syntheses, crystal structures, and magnetic properties.将二维钴（II）层转变为基于三维Co₇簇的金属有机框架：合成、晶体结构及磁性能
Inorg Chem. 2015 Mar 16;54(6):2976-82. doi: 10.1021/acs.inorgchem.5b00074. Epub 2015 Mar 2.
6
Structure-reactivity relationships in the hydrogenation of carbon dioxide with ruthenium complexes bearing pyridinylazolato ligands.含吡啶基并唑基配体的钌配合物催化二氧化碳加氢的结构-反应性关系。
Chemistry. 2013 Jun 10;19(24):7825-34. doi: 10.1002/chem.201204199. Epub 2013 Apr 15.
7
Synthesis of a novel heptacoordinated Fe(III) dinuclear complex: experimental and theoretical study of the magnetic properties.新型七配位双核 Fe(III)配合物的合成：磁性的实验和理论研究。
Dalton Trans. 2010 May 28;39(20):4874-81. doi: 10.1039/b927032a.
8
Iron-catalyzed C2-C3 bond cleavage of phenylpyruvate with O2: insight into aliphatic C-C bond-cleaving dioxygenases.铁催化苯丙酮酸与氧气的C2-C3键断裂：对脂肪族C-C键断裂双加氧酶的深入了解
Chemistry. 2007;13(21):6073-81. doi: 10.1002/chem.200601844.
9
In situ solvothermal generation of 1,2,4-triazolates and related compounds from organonitrile and hydrazine hydrate: a mechanism study.通过有机腈和水合肼原位溶剂热生成1,2,4-三唑盐及相关化合物：机理研究
Inorg Chem. 2007 Feb 19;46(4):1135-43. doi: 10.1021/ic061303i.