2-Amino-4-ferrocenyl-thia-zole.
作者信息
Anzaldo Bertin, Sharma Pankaj, Villamizar Claudia P, Gutierrez Perez Rene, Toscano Rubén A
机构信息
Instituto de Química, Circuito Exterior Cd. Universitaria, PO Box 04510, Ciudad de México, Mexico.
Lab. Síntesis de Complejos, Fac. Cs. Quím.-BUAP, Ciudad Universitaria, PO Box 156, Puebla, Mexico.
出版信息
Acta Crystallogr E Crystallogr Commun. 2022 Jul 19;78(Pt 8):818-820. doi: 10.1107/S2056989022007228. eCollection 2022 Aug 1.
The title compound, [Fe(CH)(CHNS)], was synthesized by the direct reaction of acetyl-ferrocene, thio-urea and resublimed iodine. The structure shows one mol-ecule in the asymmetric unit. The amino-thia-zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex mol-ecules inter-act inter-molecular N-H⋯N hydrogen bonds, forming a cyclic dimer which then inter-acts with other dimers through C-H⋯π inter-actions.
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